不同改良剂修复重金属cucd污染土壤的分析-analysis of different amendments for remediation of heavy metal cucd contaminated soil.docxVIP

same level with control treatments. The contents of exchange forms Cu with application of lime and apatite was decreased 99.66 mg/kg and 84.51 mg/kg in the first year, and 84.96 mg/kg and 72.96 mg/kg in the second year, Five amendments all increased the contents of carbonate form, Fe-Mn oxides bound form, organic form and residual Cu, Cd, which promoted the transformation of Cu, Cd from the active forms to the inactive ones.The amount of bacteria and fungi increased after amendments applied, and positive correlation existed between the amount of microbial and soil pH, especially for fungi, the correlation coefficient reached 0.90. The activities of hydrogen peroxidase and acid phosphatase increased with apatite, lime, charcoal application, while urease activity changed little.The soil organic matter were improved 0.65 g/kg, 0.77 g/kg and 3.39 g/kg, the soil CEC were improved 0.17cmol/kg, 0.14cmol/kg and 0.31cmol/kg, soil exchange Ca2+ were increased 2.51cmol/kg, 3.88cmol/kg and 1.05cmol/kg with apatite, lime and charcoal application. lime, charcoal decreased soil bulk 0.03 g/cm3 and 0.04 g/cm3, apatite and iron powder increased soil bulk 0.05 g/cm3 and 0.07 g/cm3, but not have obviously different with the control treatment.Results of indoor experiment showed: soil pH was increased with the application of Micro-HAP, AP and Namo-HAP, and slightly increased with time lapsed, especially the Micro-HAP was stronger than the others. Soil pH for three amendments under the same dose followed the order Micro-HAP AP Namo-HAP. The activities of hydrogen peroxidase and urease increased, and decreased acid phosphatase with Micro-HAP application, however the activities of three enzyme also increased with AP and Namo-HAP application. The concentration of Cu, Cd were studied by Toxicity Characteristic Leaching Procedure, Cu, Cd bioavailability significantly decreased with the doses increased, and Cu, Cd bioavailability for three amendments under the same dose followed the ord