不同分子构象的d-a型共轭聚合物的合成及其光伏性能的研究-synthesis and photovoltaic properties of d - a conjugated polymers with different molecular conformations.docxVIP

AbstractIn recent years, polymer solar cells (PSCs) have attracted considerable attention due to its unique features such as low cost, easy fabrication lightweight and capability to be fabricated into flexible large-area devices. However, the photovoltaic conversion efficiency (PCE) and stability of polymeric photovoltaic devices are not so high as to meet the industrial requirements. In order to get high performance of PSCs devices, it is the key to choose suitable donor and acceptor unit monomers to design and synthesize high performance D-A type conjugated copolymers. In this paper, a new view from polymeric backbone conformation will be introduced to the strategy of of design and synthesis of photovoltaic materials.As follows:1, The background and principle of polymer solar cells were introduced in chapter 1, common donor-unit and acceptor-unit used in D-A type conjugated copolymers, were summarized and classified by topological structure of monomers. Expecially, emphasis on conjugated copolymers classified by which contained topological structure units. Continuing, the paper discussed the design ideas and research contents.2, A new conjugated copolymer with Z-type backbone conformation, PBDT-TBT was synthesized by Stille couping, which used BDT as donor unit, BT as acceptor unit and thiophene as π-bridge. The photovoltaic performance of device based on PBDT-TBT was investaged by different conditions varying for acceptor materials, D/A ratio, film thickness, additives and thermal treatment. In AM 1.5G, 100mW/cm2 illumination as well as the optimal condition,which isPBDT-TBT/PC71BM ( 1:1.1, wt/wt), 1000rpm and 90℃ thermal treatment, the PCE of devicebased on PBDT-TBT was 4.9%, Voc、Jsc、FF was 0.96 V、9.22 mA/cm2、55.17 %, respectively.3, Another new conjugated copolymer with L-type backbone conformation, PBDT-TTBT was synthesized by Stille couping, which used BDT as donor unit, BT as acceptor unit and fused thiophene as π-bridge. The photovoltaic performa