吡啶2356四甲酸桥联的过渡金属多核配合物的合成 结构及性质研究-synthesis structure and properties of transition metal polynuclear complexes bridged by pyridine 2356 tetracarboxylic acid.docxVIP

ABSTRACTCompared with pyridinedicarboxylic acid，Pyridine唰2，3，5，6-tetracarboxylic acid with more coordination sites and some novel structures and coordination modes isdesiredωbe obtained ，but was much less used 50 far. By using fI4PTA as bridgingligands，novel lD chains，2D and 3D structural complexes have been successfully synthesized. Furthermore，nano-channels and coordination modes are also explained in detail...Fivecomplexes{[Cu2(PTA)(bpy)(H20)2]3 日20}n(1)， {[Cu2(PTA)(bpy)(H20)2]2H20}n (匀， {[Mn(PTA)(H20)]仙py)3日20}n (匀， {[Mn(HPTA)(H20)z](bpy)3H20CI}n (4) and {[Co3(HPTA)2(bpY)2(H20)4]4 日20}n (酌， have been synthesized and characterized by IR spectrum，thermogravimetric (丁G) analysis，ultraviolet visibleabsorption spectrum and single-crystal X-ray diffraction.Complex (1) is a binuclear structure which is assembled into 3D supramolecular network by hydrogen-bond. Complex (2) is particularly interesting in 由at it contains.nano-channels. Complex (3) 、(4) show the one-dimensional ladder-type chainsstructure. The chains are connected by hydrogen-bondωform 2D layers，the 2D layers then form 3D supramolecular framework with hydrogen-bond. There exists a (H20)6 water cluster in Complex (3). Complex (5) is a binuclear unit， and then the binuclear molecules are altematively assembled into 3D supramolecular network.The structures of them are analyzed compared with the other complexes of PTA. The hydrogen bonding of them and the different coordination modes of the carboxylategroups are analyzed in detail.、KEY WORDS: pyridine唰2，3，5，6-tetracarboxylic acid，complex，crystal structure，‘nano-channels目录第一章前言..........川..1.1 配位化学研究进展................………………........................…………… ......11.2 日比昵多酸类配合物的研究现状……………….........…………………… ......1日比院多酸类配体的配位特点…川....…….............………………川 1‘1.2.1f1.2.3 日比晚多酸类配合物的研究现状…….............................… ...................21.3逃跑依据…………............……......................................................................6啕第工章毗院寸，3，5，6-四