并列复合聚酯纤维的开发及染色性能研究-development and dyeing properties of side-by-side composite polyester fibers.docxVIP

Becausetheincreaseofthedrawingratiopromotedthemacromoleculesorientation,whichishelpfulforthecrystallization,butthehigherorientationwilldestroythecrystallizationoffiber.Generallyspeaking,whenthedrawingtemperatureis80℃,andthedrawingratiois2.1,thefibercangetthebestcrimpperformance.Throughthestudyingofheattreatmenttemperature,timeandmedia,nomatterdryorwetheattreatment,thefiber’sorientationisdecreasedwiththepassageoftime.Thefiber’smechanicalpropertiesarerelativelystable.Butcomparedwiththefiberwithoutheatingtreatment,thebreakingstrengthdecreaseswhilethebreakingelongationincreases.Thefiberisabletoachieve80%~90%oftotalcrimpratiointhefirst5minutesinwetheatingtreatment.Besidethat,thefiberwillgetthebestpropertyofcrimpat20minutesindryheatingtreatment.Theorientationoffiberdecreaseswiththehigherofheatingtreatmenttemperature.Comparingwiththefiberwithoutheatingtreatment,thebreakingstrengthdecreaseswhilethebreakingelongationincreases.Thebestwetheattreatmenttemperatureoffiberis90℃,and140℃isthebestdryheattreatmenttemperature.Thepropertyofcrimpbyhotwaterishigherthanthattreatedbyhotairduetotheplasticizingofthewatermolecules,fromtheenergysaving,thebestwayofthefiberheattreatmentis90℃,5minutesinhotwater.DuringPET/ECDPside-by-sidebicomponentpolyesterfiberdispersedyeingprocess,hightemperatureandhighpressureconditionisnecessary.BothofPET/ECDPpartswillgetcolor,andit’swasteofenergy.Byusingcationicdye,theprocessissimple,anditcangetgoodeffectonapparent.Thedyeingrateofthefiberwillbehigherwithlowdrawingtemperature.Becausethereismorecomponentofamorphousarea,especiallyinECDP,thelowerofdrawingtemperatureis,easierfordyemoleculesgettingintothefiber.Thehigherofdyeingtemperature,thefabricwillgethigherK/Svalue.Thisisduetocationicdyemoleculesandionicbondofthesulfonicacidgrouparemoreactiveinhighertemperature.ShiYuan(MaterialEngineering)Supervisedby:ProfessorWangHuaping,WangChaoshengKEYWORDS:side-by-sidecompositepolyesterfiber,FDY’onestep’process,heattreatment,crystallinityandorientation,dye目录摘要iABSTRACTiv第一章