固体超强酸so42-tio2的改性及其催化合成柠檬酸三丁酯的研究-study on modification of solid superacid so42 - tio _ 2 and its catalytic synthesis of tributyl citrate.docxVIP

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固体超强酸so42-tio2的改性及其催化合成柠檬酸三丁酯的研究-study on modification of solid superacid so42 - tio _ 2 and its catalytic synthesis of tributyl citrate.docx

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固体超强酸so42-tio2的改性及其催化合成柠檬酸三丁酯的研究-study on modification of solid superacid so42 - tio _ 2 and its catalytic synthesis of tributyl citrate

摘摘要汕头大学工学硕士学位论文汕头大学工学硕士学位论文万方数据万方数据万方数据万方数据4Studies on Modification of Solid Super Acid SO 2-4/TiO2 and Synthesisof Tri-n-butyl Citrate with the catalystAbstractTri-n-butyl citrate(TBC) was synthesized with solid super acid as catalyst, and the catalytic properties of the catalyst SO42-/TiO2 in esterification of citric acid with n-butanol were studied. A new catalyst Tm-SO42-/TiO2 was prepared by modification on which the rare earth element Tm was loaded. The correlation between its structure and properties was also investigated. All these above strongly support the industrializationof TBC synthesis catalyzed by solid super acid.This paper reported the esterification synthesis of TBC under no catalyst, H2SO4, or solid super acid SO42-/TiO2. The correlation between reaction conversion, water yield and reaction time was surveyed. The effects of initial molar ratio and catalyst quantity were investigated and the optimum synthesis conditions were found. Tri-n-butyl citrate was synthesized with solid super acid SO42-/TiO2 as catalyst, and the activity and stability of the catalysts in esterification of citric acid with n-butanol were studied. Theeffects of (NH4)2SO4 quantity and calcination temperature on the catalysts were studied and the correlation between their structure and properties was also investigated. The results showed that (NH4)2SO4 was better than H2SO4 as promoter. The catalyticselectivity amounted to 99% while 20% (NH4)2SO4 added and 600℃ calcinated. Onthis condition the conversion of citric acid was 92.7%, and the ester yield was 92.3%. The formation and growth of anatase crystalline phase was the key factor in the improvement of catalytic selectivity. The deactivation of catalysts in TBC synthesis2-resulted from the carbon deposition and the loss of SO4 .2-In order to improve catalytic properties, Tm-SO4/TiO2 was prepared bymodification, the rare earth element Tm was loaded on SO42-/TiO2. Loading Tm effectively promoted