磁性稀土上转换复合材料β-nagdf4yb,er的制备-preparation of magnetic rare earth upconversion composite β - na gd f4yb, er.docxVIP

PAGE PAGE VI物相容性。关键词：纳米材料，上转换荧光，磁性材料，NaGdF4AbstractLanthanide-based upconversion nanoparticles(UCNPs)that emit high-energyphotons under excitation by near-infrared(NIR)low-energy light have been widelyexplored in recent years for their potential applications in nanomedicine.Comparedwith traditional down-conversion fluorescent dyes and quantum dots(QDs),UCNPspossess of many advantages,such as low toxicity,high chemical and optical stability,deep light-penetration under NIR excitation,minimal photodamage to living organisms,and nearly-zero background auto-fluorescence.In my work,at first,series of small sized NaGdF4:Yb,Er nanoparticles(NPs)were fabricated via facile hydrothermal process.It can be seen from TEM images that NaGdF4:Yb,Er NPs possess uniform sizes and have very good dispersibility inethanol. High bright yellow luminescence were observed when NaGdF4:Yb,Er NPs were under 980nm laser. Then,to transfer these hydrophobic NPs to be hydrophilic,a very facile method was investigated.Monodispersed Fe3O4 magnetic NPs sized in~10 nm were synthesized via hydrolyze under alkaline conditions. they that emitted a bright yellow light under a 980-nm laser,Via were fabricated adjust Yb and Gd ions.To synthesize Fe3O4/NaGdF4:Yb,Er nano-composites,three fabricating strategies were studied.(1)Fe3O4/NaGdF4 submicro-rods were synthesized via a facile hydrothermal process .A large number of Fe3O4 NPs were firmly attached on the surface of NaGdF4 nano-rods to form a hetero structure.The SP property and UCL property of Fe3O4/NaGdF4 hetero nano-rods were studied by luminescence spectrum,which which is higher than reported figures,and they emitted a bright yellow light under a 980-nm laser.These demonstrates that Fe3O4/NaGdF4 nano-rods performed obviousbifunctional superparamagnetic and upconversion luminescent properties. (2)NaGdF4:Yb,Er/Fe3O4-SiO2 nano-composites were fabricated via a SiO2coating method.From their TEM images we found that multiple~10nm Fe3O4 NPs andsin