钯合金与铑电沉积及纳米线制备-electrodeposition of palladium alloy and rhodium and preparation of nanowires.docx

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2018-07-28 发布于上海
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钯合金与铑电沉积及纳米线制备-electrodeposition of palladium alloy and rhodium and preparation of nanowires.docx

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钯合金与铑电沉积及纳米线制备-electrodeposition of palladium alloy and rhodium and preparation of nanowires

钯合金与铑的电沉积及纳米线的制备AbstractAttentionismoreincreasinglypaidtoMetalsinplatinumclanowingtotheirgoodspecialproperties.Palladiumalloysareusedashydrogen-sensingorganswhicharenotinvalidatedinhighhydrogenconcentrationsurroundingsandhavepropertiesofgoodhydrogen-adsorptionreversibility,fastresponseandanti-H2Spoisonability.Platingcoatingofpalladium-cobaltalloyhaselegantfaces,highhardness,lowporiness,goodcorrosionresistanceandlowcontactresistanceaswellasgoodweldability,whichcanreplacehardgoldcoatingforhightemperatureautomobileparts,electronicconnectorplugs/jacksandjewelry.Rhodiumcoatingwithsilverywhitecolourisextensivelyappliedinjewelryandelectronicindustrysinceithasgoodwearabrasionresistanceandchemicalstability.Theinvestigationworksaresummizedasfollows:ElectrodepositionofnanowiresofPd-NiandPd-Agalloysbyelectroch-emicalstepedgedecorationmethodElectrochemicalcodepositionbehaviorsofPd,Ni,AgandtheiralloysintheammoniacomplexbathsandeffectsofthebathcompositionandthedepositionprocessesonthealloycompositionofPd-NiandPd-Aghavebeeninvestigated.AlloynanowiresofPd-NiandPd-Agweresuccessfullysynthesizedonthesubstrateofhighlyorientedpyrolyticgraphitebyelectrochemicalstepedgedecorationmethodforthefirsttime.ThealloycompositionsofPd-NiandPd-AgweredeterminedbyInductivelyCoupledPlasmaAtomicEmissionSpectrum(ICP-AES).ThemorphologiesandcompositionsofPd-NiandPd-AgalloynanowireswerecharacterizedbySEMandEDS.Theresearchresultsaresummarizedasfollows：InvestigationofelectrodepositionofPd,Ni,Agandtheiralloysbypolarizationmethodandcyclicvoltammetricalexperiments,whichshowthatpolarizationdegreeofnickelislargerthanthatofpalladiumandobviouslypalladiumcatalysestheelectrodepositionofnickel,butnickelslightlyhinderstheelectrodepositionofpalladium.Theevolutionofhydrogenisthemainconcomitantreaction.WithpHvalueincreasing，hydrogenevolvesexceptionalandcurrentefficiencywilldecrease.ThepHvalueshouldbecontrolledto8.5.Codepositionofpalladiumandsilverdemonstratestheabnormalcodepositionmechanism.Silverunder-depositsonthesurfaceo