镍基niruo2复合电极和ni-p合金电极的制备及其催化析氢性能的研究-preparation of ni - based ni ruo 2 composite electrode and ni - p alloy electrode and study on their catalytic hydrogen evolution performance.docxVIP
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镍基niruo2复合电极和ni-p合金电极的制备及其催化析氢性能的研究-preparation of ni - based ni ruo 2 composite electrode and ni - p alloy electrode and study on their catalytic hydrogen evolution performance
forHERislowerthanthatofNi/RuO2,duetowithoutasynergisticeffectbetweentheTisubstrateandRuO2.TheNi-Palloyelectrodewaspreparedbyoxalicacidetchingandpulseelectrodepositionmethod.Themorphology,structureandcompositionoftheas-preparedelectrodeswerecharacterizedbySEMandEDS.ThecatalyticperformanceandstabilityoftheelectrodesforHERwereevaluatedbyLSVandCP.ExperimentalresultsshowthatNi-Palloyelectrodeiscomposedofclose-packedparticleswithsponge-likemicrostructure,whichishelpfulforincreasingthesurfaceroughoftheelectrode,aftertheNisubstrateetchedbyoxalicacid.Comparedwiththeelectrodeobtainedbydirectcurrentelectrodeposition,Ni-Palloyelectrodepreparedbypulseelectrodepositionexhibitsalowerover-potentialforHER.Thereasonisthatpulseelectrodepositioncanrefinetheparticlesontheelectrodeandincreasespecificsurfacearea.Inaddition,Phosphorusplaysanimportantroleinpromotingthegrainrefinementandimprovingtherateofdehydrogenationonelectrode.Therefore,Ni-Palloyelectrodeexhibitsexcellentcatalyticactivityandlong-termstability.Keywords:HydrogenEvolutionReaction(HER),Electrocatalysis,CompositeElectrode,Alloy,WaterElectrolysis目录中文摘要..........................................................................................................................................I英文摘要........................................................................................................................................II1绪论.........................................................................................................................................11.1氯碱工业简介...........................................................................................................................11.1.1氯碱工业的发展................................................................................................................11.1.2氯碱工业的基础化工生产................................................................................................21.1.3氯碱工业的电解原理和生产工艺................................................................................
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