溶胶－凝胶法制备的pegsio2定形相变材料的研究-study on pegs io 2 shaped phase change material prepared by sol-gel method.docxVIP

AbstractAbstractThesurfacetemperaturecontrolisoneofthemaintechniquesatinfraredstealth.Thephasechangematerialscanconverttheheatorthesolarenergytothelatentheatandstorethem,sothesurfacetemperatureoftheobjectwillnotchangeviolently.Inrecentyears,thephasechangematerialshavealatentappliedprospectinthefieldoftheinfraredstealthymaterials,havealreadybeenpaidattentiontobypeoplegradually.Thecommonphasechangematerialswillbecometheliquidatthesolid–liquidphasechange,andacontainermustbeusedtocontainthem,whichwillresultintheinconvenienceattheactualusage.Inthisthesis,polyethyleneglycol(PEG)isthephasechangematerial,silicondioxide(SiO2)derivedfromtetraethylorthosilicate(TEOS)isthecarrier,ThePEG/SiO2compositeform-stablephasechangematerialsarepreparedbySol-Gelapproach.ThebasicsynthesismechanismsofPEG/SiO2havebeenanalyzed,thenovelmaterialsandprocessareexploredandinvestigated.Themainresultsareasfollows:ThenewtechnicsofproductionofthePEG/SiO2form-stablephasechangematerialsbySol-Gelapproachisresearched.InSol-Gelreaction,TEOSistheforerunner,PEG1500,PEG2000,PEG4000,PEG6000,PEG10000arethephasechangematerials,ethanolisthesolvent,hydrochloricacidistheactivator.ThePHoftheadmixtureis1,thetimeofripeningis4hours,thetemperatureofripeningis40℃,thetimeofripeningisnotlessthan24hours,thetemperatureofdesiccatingis80℃,thetimeofdesiccatingisnotlessthan3days.TheirmostweightpercentagesofPEGwithdifferentmolecularweightare80％-83％inthePEG/SiO2form-stablephasechangematerials.PEGdon’tseepat80℃after24hours.Thephasechangetemperatureis47.58℃~63.26℃,andthephasechangeenthalpyis73.70J/g~131.3J/gbyDSC.thedensityis1.220g/cm3~1.301g/cm3bySpecificGravityBottlemethod,theconstanttemperatureis38.9℃~51.8℃,thetimeofcontrollingtemperatureis15~20minutesbystepcoolingcurvetest.AbstractThefactorsofaffectingthermalpropertiesofthePEG/SiO2form-stablephasechangematerialsarestudiedindetailandtherelativemechanismsarediscussed.Thephasechangeenthalpyandthephasechangetemperatureofform-stablephasechangematerialsincreasewiththemolecularweightofP