生物基锦纶56结构与性能-structure and properties of bio-based nylon 56.docxVIP

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生物基锦纶56结构与性能-structure and properties of bio-based nylon 56.docx

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生物基锦纶56结构与性能-structure and properties of bio-based nylon 56

万方数据万方数据 Structure and Properties of Bio-based Polyamide 56 Abstract In this paper, structure and properties of bio-based PA56 were characterized by FT-IR, DSC, TG, XRD, GPC and SEM, and compared with PA6 and PA66. PA56 was dyed with weak acid dyes, neutral dyes and disperse dyes, and the dyeing process curves of PA56 was determined. Fastness were measured, and the dyeing thermodynamics and kinetics of polyamide were investigated. The main conclusions of the paper are as follows: The melting point of PA56 fiber (254.1℃) close to PA66 (249.3℃), and higher than PA6(224.2℃). The degree of crystallinity of PA56 is 57.6%, less than PA6, PA66. The regain of moisture absorption and desorption of bio-based PA56 are larger compared with PA6, PA66. The moisture desorption rate and dry rate of PA 56 is the fastest. The acid and alkali resistance properties of bio-based PA56 compared with the normal polyamide are slightly worse. The dyeing thermodynamics of polyamide fibers with acid blue NHFS, neutral dark yellow GL and disperse Blue 2BLN were studied. The types of adsorption isotherms were obtained and the dyeing saturation values were compared. The kenetic results showed that the average diffusion coefficient and dyeing rate constant of PA56 were significantly higher than PA6, PA66 when they are dyed by acid blue NHFS and neutral dark yellow GL at the same dyeing temperature, its half dyeing time is the shortest. The slope of dyeing rate curves have little difference at the same dyeing temperature when polyamide fibers were dyed by disperse blue 2BLN, which indicates that the uptake rate of disperse blue 2BLN on three fibers have little difference. Key words: bio-based PA56; PA6; PA66; structure; moisture absorption; acid and alkali resistance; dyeing III IV 目录摘要 ................................................................................................................................................ Ⅰ Abstract ...........................................