石煤提钒尾渣地聚物的制备及其机理的分析-preparation and mechanism analysis of geopolymer from vanadium extraction tailings from stone coal.docxVIP

制备地聚物的3d、7d和28d抗压强度分别提高了28.492MPa、27.674MPa和22.263MPa，并且在28d内未出现“泛霜”问题。（3）石煤提钒尾渣地聚物的反应机理研究通过XRD、FTIR和SEM及化学成分的定量分析等方法对最佳工艺条件下的不同龄期的地聚物制品进行了研究，分析出了石煤提钒尾渣地聚物的形成过程包括火山灰反应和地聚合反应两个部分，碱硅铝酸盐凝胶、少量的类沸石矿物生成和C-S-H凝胶的共同存在，使得活化后尾渣制备的地聚物试样抗压强度大幅度增大。（4）石煤提钒尾渣的活化机理研究通过对尾渣活化前后的活性测定和XPS分析及尾渣活化前后分别制备的地聚物制品的XRD、FTIR、EDS和孔径分析表明：尾渣经过活化后，矿物的聚合度变低，矿物结构变得不稳定，表面反应活性增大，胶凝性提高；活化尾渣制品中胶凝产物增加，使得制品中的无害孔增多，有害孔减少，比表面积大幅度增大，从而使得制品强度提高，并在28内抑缓解了“泛霜”现象。关键词：石煤提钒尾渣地聚物工艺活化机理IIAbstractWiththerapiddevelopmentofextractingvanadiumfromstonecoal,emissionsoftailingshasgraduallyincreased,amountsoftailingscausedwasteofresourcesandlandshortageandpollutionoftheenvironmentandsecurityrisksandotherissues,increasedthecostofproduction,butalsoseriouslyhampersustainabledevelopmentofvanadiumextractionindustry.Geopolymerisanewdevelopingcementitiousmaterialinrecentyears,whichconsistsofsiliconaluminummaterialsundertheactionofalkalineactivatorwithappropriatetechnology.Theproductsshowagoodperformanceandhasgreatprospects.AsthestonecoalvanadiumtailingshaveahighcontentofAlandSi,thetailingscanbeusedasbasematerialstoprepareforgeopolymer.Fromtheperspectiveofresourceutilization,protectionofenvironment,onlinecirculationandzeroemissionsofthesecondaryresources,utilizingtailingtoprepareforgeopolymerhasgreatenvironmentalbenefits,socialandeconomicbenefits.Onthebasedofthestudyofthepropertiesofvanadiumtailings,thestudyresearchedthatvanadiumextractiontailingsasthemainrawmaterialswereusedtoprepareforgeopolymer,mainlyincludingtheprocessconditionsofusingthevanadiumtailingsandactivatedvanadiumtailingstoprepareforgeopolymer,discussingtheactivationmechanismofvanadiumtailings,theperformanceandstructureandreactionmechanismofgeopolymerproducts.Thecontentsandresultsareasfollows:StudyingonvanadiumtailingsweredirectlypreparedforgeopolymerThecharacteristicsofvanadiumtailingswereanalyzed,includingchemicalcomposition,mineralcomposition,particlesizedistribution,morphology,ashactivityandotherperformanceanalysis;Havingdeterminedthebestpreparationconditionsoflvan