石灰石颗粒磨损特性与机制分析-analysis of wear characteristics and mechanism of limestone particles.docxVIP

重庆大学硕士学位 重庆大学硕士学位论文 英文摘要 PAGE PAGE IV impact increases with attrition times with a function of linear correlation. Surface attrition becomes intenser and breakage of large particle takes dominant position when initial particle size decreases. Attrition effect of limestone particles in fluidized bed is not symmetrical with increasing time.Cumulative mass fraction of limestone fines increase with attrition time with a function of decaying exponential correlation. Attrition is stronger with increasing initial particle size in high temperature. And attrition becomes tougher at higher fluidized velocity. Two turning points of temperature are 500 ℃ and 750 ℃. Stair-shaped and texture-shaped are two different particle surfaces which form under high temperature. Lots of texture-shaped surface particles and special parallel cracks are found in thermogravimetric analyzer attrition test. This study enriches the achievements of attrition mechanism of limestone particles. It promotes in-depth study of calcium-based sorbents attrition in fluidized bed. Results provide experimental and theoretical basis for utilization of calcium-based sorbents in fluidized bed. Keyword: Limestone particles, particle attrition, particle impact, decay rate, particle size distribution 重庆大学硕士学位论 重庆大学硕士学位论文 目 录 目 录 中文摘要I 英文摘要 II 1 绪 论 1 1.1 研究背景、意义及课题来源 1 1.2 石灰石颗粒磨损概述 2 1.2.1 石灰石颗粒磨损分类 2 1.2.2 石灰石颗粒磨损机理 4 1.2.3 石灰石颗粒磨损机制研究方法 5 1.3 影响石灰石颗粒磨损的因素 10 1.3.1 物性因素对磨损的影响 10 1.3.2 流化条件及其他处理的影响 11 1.3.3 描述磨损的方法 14 1.4 本文主要的研究内容 16 2 实验系统设计、物料及评价指标 17 2.1 实验原料的物化性质 17 2.2 实验装置系统 17 2.2.1 磨损装置设计及主要参数 17 2.2.2 实验参数的测量 23 2.3 评价指标 23 2.4 本章小结 24 3 石灰石颗粒机械磨损特性与机制研究 25 3.1 石灰石颗粒的碰撞破碎特性 25 3.1.1 碰撞速度的影响 25 3.1.2 碰撞角度的影响 27 3.1.3 碰撞次数的影响 30 3.2 石灰石颗粒在流化床中的磨损特性 32 3.2.1 初始粒径的影响 32 3.2.2 流化风速的影响 33 3.2.3 磨损时间的影响 36 3.3 石灰石颗粒机械磨损机制研讨 39 3.4 本章小结 39 4 石灰石颗粒热力磨损和化学磨损特性与机制研究 41 4.1 粒径和风速对石灰石颗粒热力磨损的影响 41 4.1.1 热态下初始粒径对石灰石颗粒磨损特性的影响 41 4.1.2 热态下流化风速对石灰石颗粒磨损特性的影响 42 4.2 床层温度对石灰石颗粒热力磨