影响溶剂的结构、形态和性能H2 cd solvothermal准备的论文方法的进化：（Influence of the solvent on the structure, morphology and performance for H2 evolution of CdS photocatalysts prepared by solvothermal method）.pdfVIP

Applied Catalysis B: Environmental 203 (2017) 753–767 Contents lists available at ScienceDirect Applied Catalysis B: Environmental j o u r na l h o m e p ag e: w w w. elsev /locate/apc atb Influence of the solvent on the structure, morphology and performance for H2 evolution of CdS photocatalysts prepared by solvothermal method F. Vaquero, R.M. Navarro ∗ , J.L.G. Fierro Instituto de Catálisis y Petroleoquímica, CSIC, C/Marie Curie 2, Cantoblanco, 28049 Madrid, Spain a r t i c l e i n f o a b s t r a c t Article history: CdS crystals with different morphologies, nanorods, sheets, microspheres and irregular particles Received 27 June 2016 have been obtained by changing the solvothermal solvent (ethylenediamine, diethylenetriamine, tri- Received in revised form 21 October 2016 ethanolamine and ethanol). Characteristics of the solvothermal solvents, such as dielectric constant, Accepted 26 October 2016 ion-coordination and length of an atomic chain, have influence on the nucleation and growth of CdS Available online 27 October 2016 crystals. The differences in the morphological and structural characteristics of the CdS crystals have strong influence on their photophysical properties as well as in their photoactivity for hydrogen pro- Keywords: duction under visible light from aqueous solutions containing Na SO and Na S as sacrificial electron CdS