一项研究支持表面属性之间的协同和二氧化碳重整催化剂失活对镍纳米粒子的支持:(A study of the synergy between support surface properties and catalyst deactivation for CO2 reforming over supported Ni nanoparticles).pdfVIP

一项研究支持表面属性之间的协同和二氧化碳重整催化剂失活对镍纳米粒子的支持:(A study of the synergy between support surface properties and catalyst deactivation for CO2 reforming over supported Ni nanoparticles).pdf

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Applied Catalysis A, General 545 (2017) 113–126 Contents lists available at ScienceDirect Applied Catalysis A, General journal homepage: /locate/apcata Research Paper A study of the synergy between support surface properties and catalyst T deactivation for CO2 reforming over supported Ni nanoparticles a a b a,⁎ Subhasis Das , Manideepa Sengupta , Jim Patel , Ankur Bordoloi a Nanocatalysis area, Refi nery Technology Division, CSIR–Indian Institute of Petroleum, Dehradun, 248005, Uttrakhand, India b CSIRO Energy, 71 Normanby Rd., Clayton North 3169, Australia A R T I C L E I N F O A B S T R A C T Keywords: The correlation between surface acidity-basicity and catalyst deactivation have been investigated in the CO2 Dry reforming reforming of methane by adjusting the surface properties of the catalyst. Silica and alumina based support with Metal support interaction different acidity-basicity have been prepared by two methods, (i) a solvothermal method and (ii) a sequential Surface acidity-basicity impregnation method. Then each of the supports has been decorated with Ni nanoparticles followed by variation Kinetics of their activity towards CO2 reforming of methane (DRM). The catalytic materials have been analyzed before

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