球磨remg11nix％nire=la,ce,pr,nd；x=100,200型合金的储氢性能研究-球磨rem 11nix % nire = 1a、铈、镨、钕；x = 100，200型合金的储氢性能研究.docxVIP

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球磨remg11nix％nire=la,ce,pr,nd；x=100,200型合金的储氢性能研究-球磨rem 11nix % nire = 1a、铈、镨、钕；x = 100，200型合金的储氢性能研究.docx

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球磨remg11nix％nire=la,ce,pr,nd；x=100,200型合金的储氢性能研究-球磨rem 11nix % nire = 1a、铈、镨、钕；x = 100，200型合金的储氢性能研究

内蒙古科技大学硕士学位论内蒙古科技大学硕士学位论文 II II Abstract Along with excessive exploration and utilization of some non-renewabable resources such as coal, oil and gas, the energy crisis is more and more serious in today’s society, what’ more, environment pollution has seriously affect the human’s normal life, especially, the fog whether has brought on lots of inconvenience for human life which appears constantly in some cities recently. However, the chief culprits of the over pollution is due to excessive emission of the vehicle exhaust, the unreasonable development and utilization for coal and some other fuel resources. Therefore, in order to make up the increasingly dried up non- renewabale resource, the development of new energy is imminent. Among lots of energy, hydrogen energy stands out for its unique advantages as a clean energy. And it is always the focus of international scholars for the research of hydrogen storage and transporation. However, the hydrogen storage alloy is the best way for the storage of hydrogen. In the numerous hydrogen storage alloys, the Rare earth Mg-based hydrogen storage alloy attracts international scholar’s attention because of its unique advantages, such as high hydrogen absorption capacity, high discharge capacity, low cost and slight quality. The REMg11Ni (RE=La Ce Pr Nd) hydrogen storage alloys are prepared by induction melting method under the protection of He at the pressure of 0.04Mpa which is under the condition of negative pressure in order to reduce the volatilization of RE and Mg . Then, the as-cast alloy is obtained, which is broken into power below 75 μm, and then mixed with x% (x=100 200)Ni power for ball milling to obtain balling milled hydrogen storage. The maximum discharge capacity of the ball milled REMg11Ni (RE=La Ce Pr Nd) hydrogen storage with 200% Ni power is 1053.5、1040、1135.5、1079.8mAh/g, which are higher than the as-cast REMg11Ni (RE=La Ce Pr Nd) hydrogen storage alloys and ball milled with 100%Ni power. In the aspect of