水性形状记忆聚氨酯的合成及性能分析-synthesis and properties analysis of waterborne shape memory polyurethane.docxVIP

水性形状记忆聚氨酯的合成及性能研究 水性形状记忆聚氨酯的合成及性能研究 A Abstract III III Ⅳ Ⅳ 稳定性，且涂膜的耐水性和记忆性能良好。 6. 并且在利用涂层，将不同浓度的水性形状记忆聚氨酯涂覆到丝绸上，制得含有一定 量形状记忆聚氨酯的丝绸材料，并对其结构性能等进行了测试。结果表明，经水性形状记忆 聚氨酯处理后的丝绸产品具有很好的形状记忆功能，成为形状记忆的丝绸产品。 关键词：水性聚氨酯；智能聚合物材料；形状记忆；合成；性能。 Abstract The research of smart polymers has become the hottest field of materials. Many countries are researching and developing the novel functional materials. The waterborne shape memory polyurethane studied in this article is the most notable smart material because of excellent properties and broad using field. In this paper three series of waterborne shape memory polyurethane were synthesized and the properties were studied. he main contents of this thesis include the following points: The preparations of waterborne polyurethane were reviewed，and the development of aqueous polyurethane and modified aqueous polyurethane was summarized. At the same time，the research progress of solvent shape memory polyurethane at home and abroad in the recent years was introduced, through making comparative analysis with regard to the advantages and disadvantages of different methods,we look to the orientation of future development. Lastly the novel crosslinked waterborne shape memory polyurethane was synthesized, which can completely recover original shape. The properties of polyurethane were studied, including calorifics, dynamic mechanism and shape memory. Comparing to the liner shape memory polyurethane. The crosslinked polyurethane has completely shape memory behavior. Networking waterborne shape memory polyurethane(WSPU) was synthesized from TDI, PCL, DMPA and TMP. Their shape-memory behaviors were investigated as a function of PCL molecular weight and hydrophilic-chain-extender. FT-IR, 1H-NMR, DSC and Shape memory testing indicated that When the content of soft-to-hard content is certain , the degree of soft segment crystallization enhances with increasing molecular weight of PCL .The molercular wight(Mn) of PCL was 5000,and the recovery r