碳酸盐基稀燃nox储存还原催化剂的结构与性能分析-structure and performance analysis of carbonate - based lean burn nox storage and reduction catalyst.docxVIP

hydroxyl groups but more accessible surface carbonate species; when the calcination temperature of the support is increased to 850 oC, the specific surface areas of the support decline evidently, which is unfavorable to the dispersion of K species, leading to the formation of more bulk or bulk-like K2CO3 species. The catalyst Pt-25%K2CO3/Al2O3 exhibits a very large NOx storage capacity (2.53 mmol/g) and a very high NOx reduction percentage (99%). When K2CO3 loading is very low (less than 10%), most of the K2CO3 reacts with the surface hydroxyl groups on Al2O3, forming surface –OK groups, as a result, little surface K2CO3 is detected. On the contrary, as the K2CO3 loading is higher than 10%, the surface K2CO3 species are obviously formed. The largest amount of surface K2CO3 is achieved on Pt-25%K2CO3/Al2O3. Further increase of K2CO3 loading leads to the formation of more bulk or bulk-like K2CO3 species, decreasing the NOx storage and reduction performance of the catalysts. KEY WORDS: NOx storage and reduction; carbonate; K species; distribution; structural characterization 目 录 HYPERLINK \l _bookmark0 第一章 绪 论1 HYPERLINK \l _bookmark1 1.1 课题研究背景1 HYPERLINK \l _bookmark2 1.1.1 汽车尾气污染概况1 HYPERLINK \l _bookmark3 1.1.2 稀薄燃烧技术2 HYPERLINK \l _bookmark4 1.2 稀燃条件下NOx的催化消除技术 2 HYPERLINK \l _bookmark5 1.2.1 NO直接分解技术 2 HYPERLINK \l _bookmark6 1.2.2 NOx选择催化还原技术（SCR） 4 HYPERLINK \l _bookmark7 1.2.3 碳烟和NOx共同消除技术 5 HYPERLINK \l _bookmark8 1.2.4 NOx储存-还原催化技术（NSR） 6 HYPERLINK \l _bookmark9 1.3 NSR催化剂的组成及抗硫性能 7 HYPERLINK \l _bookmark10 1.3.1 NSR催化剂的组成 7 HYPERLINK \l _bookmark11 1.3.2 硫中毒及抗硫性能的改进8 HYPERLINK \l _bookmark12 1.4 本论文的研究思路和内容10 HYPERLINK \l _bookmark13 1.5 论文创新点11 HYPERLINK \l _bookmark14 第二章 碳酸盐基Pt-K2CO3/ZrO2 催化剂储存性能的研究 12 HYPERLINK \l _bookmark15 2.1 引言12 HYPERLINK \l _bookmark16 2.2 实验部分12 HYPERLINK \l _bookmark17 2.2.1 实验所用药品和试剂12 HYPERLINK \l _bookmark18 2.2.2 催化剂制备方法12 HYPERLINK \l _bookmark19 2.2.3 催化剂表征13 HYPERLINK \l _bookmark20 NOx储存性能测试（N