无掺杂k0.5na0.5nbo3压电陶瓷a位非化学计量比变化对其结构的影响-influence of non-stoichiometric a - position changes on the structure of undoped k 0.5 na 0.5 nbo3 piezoelectric ceramics.docxVIP

ABSTRACTK0.5Na0.5NbO3basedceramicpossessesexcellentpiezoelectricpropertiesandhighCurietemperaturewhentheNa/Kratioisaround50/50becauseofthepresenceofamorphotropicphaseboundary(MPB).SinceSaitoel.al.developedatexturedKNN-basedceramicwhosepropertieswerecomparablewithPZTsystem,moreandmoreattentionshavebeenpaidtoKNN-basedpiezoceramics.Inthispaper,theattemptstoimprovethesinterabilityandphysicalpropertiesofK0.5Na0.5NbO3bychemicalmodificationwereintroducedindetail.Andthecrystalstructureandmicrostructureofun-dopedpotassiumniobatesodiumbasedlead-freepiezoelectricceramicswerestudiedbychangingA-siteelementsstoichiometry.Themajorconcerningof(K0.5+xNa0.5+y)NbO3ceramicsistheproblemofobtainingsampleswithhighdensitybyconventionalsolidstatesinteringmethod.TheevaporationoftheA-siteelementKandNaleadstothedegrationofelectricpropertiesandsinteringability,therefore,InvestigatingtheinfluenceofA-sitenon-stoichiometryonthestructureandpropertiesofun-dopedKNNbasedleadfreepiezoelectricceramicareofgreatsignificance.Inthiswork,weattempttofabricateKNNsamplesbytraditionalsolidstatemethodassistedbymechanicalactivationtopreparenano-scaleceramicpowder.FromtheXRDpattern,WhenA-siteelements(KandNa)stoichiometryhaveasmalldeviation,therewillbeaphasetransitionfromorthorhombictoquasi-tetragonalwhentheamountofKandNadecrease.TheemergenceofMPBgreatlyenhancethesinteringproperties,relativedensityandphysicalpropertiesoftheKNNceramicsamples.CombiningwiththeRamanandFourierinfraredspectroscopycanfurtherfindthatA-siteelementvariationhavegreatimpactonniobiumoctahedralligandfieldleadtothealterationofO-Nb-Obondlengthandenergyandthelatticeparameterwillaccordinglychange,too.FromSEMimages,itcanbefoundexcessalkalinemetalisbeneficialtoformliquidphaseandincreasematerialdensity,ButwhentheamountofexcessKorNareachto1.5%or1%,respectively,grainabnormalgrowthappear,andthesampleswillbeeasydelinquent.WhenthedeficiencyofbothKandNaareupto1.5%moltherewillbetungstenbronzestructureK5.75Nb10.85O30precipitate.However,WhentheexcessamountofKand