钛网表面二氧化钛纳米管的制备与光催化特性分析-preparation and photocatalytic properties analysis of titanium dioxide nanotubes on titanium mesh surface.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 Abstract In this study, titania nanotubes are anodized in the titanium net, and the nitrogen-doped nanotubes are obtained by i on implantation. The morphology, crystalline structure, chemical composition, microstructure and photocatalytic properties of the nanotubes and the N-doped ones are discussed. The different morphologies of nanostructure are fabricated in Ti net by anodization combined with different technological processes. SEM shows that ridge-like nanostructures including nanopores and naonotubes on Ti net are radial pattern. However, of all processes, Ti net is mainly coated by nanotubes which is fabricated without chemical polishing pretreatment. On the top of the ridge, part of the nanotubes are flattened, which can be wiped off afer ultrasonic vibration and the dependent and complete nanotubes are obtained. It is obvious that without chemical polishing, the fabrication processing is simplified. The average inner pore diameter calculated from the SEM images is between 80nm and 120 nm, wall thickness 30 to 45nm and tube length upon 4μm. The GXRD results indicate that TiO2 nanotubes is amorphous before annealing. It can be seen that the crystalline nanotubes occurs in anatase at a temperature of 450℃. Anatase transformed into rutile between 450 ℃ and 550℃ annealing.With the rising of the temperature,the content of the rutile increase. Compared with the samples with ultrasonic final treatment, the weight fraction of rutile with stirring is more. The TEM results reveal that, annealing at 550 ℃, the single nanotube is anatase and the oxide on the surface consist of polycrystalline particles with both anatase and rutile phase. It is found that defects like stacking faults are generated from the surface after ion implantation. The XPS patterns shows that there are three kinds of elements including tinanium, oxygen and carbon in the surface of the nanotube and after ion implantation adding nitrogen. The high - reso