无铅bt-bkt陶瓷体系的初步研究-preliminary study on lead-free bt - bkt ceramic system.docxVIP

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无铅bt-bkt陶瓷体系的初步研究-preliminary study on lead-free bt - bkt ceramic system.docx

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无铅bt-bkt陶瓷体系的初步研究-preliminary study on lead-free bt - bkt ceramic system

华华中科技大学硕士学位论文 II II Abstract Due to the restrictions of hazardous substances for imports and exports from European Union lead-free PTC has been studied during the recent years, it has become a hot spot. It belongs to environmentally friendly material and also can be used in electronics information, lead-free PTC has abroad prospects. the power of BKT and BT were prepared, meanwhile we also selected the different temperatures to sinter, it was sure that the power of BKT should be sintered at 800℃, and the power of BT should be sintered at 1150℃. In order to obtain the decent performance, in the experiment we also change the technological process. In the second we study the system of BT-BKT, and obtained the property of PTC but also the lower room-temperature resistivity. We chose the content of 5mol%, sintering temperature of the powers was also considered. the room temperature resistivity of the ceramic was 3.5×104Ω.cm, Curie temperature was 156.8℃and the ratio between the maximum resistance and the minimum resistance was103.In the end we chose the different experimental ion-doped PTC ceramics to discuss the PTC property. We chose Sm3 + and Nb5 + as donor-doped elements. We found it difficult to achieve semiconducting ceramics using trivalent-doped, but Nb5 + can get a lower room temperature resistivity. We also used the equivalent of Ca2+ ions to dope, the mechanism was discussed and the optimum content was 5mol%. In this paper the PTC ceramic with low temperature resistivity and high Curie temperature point was prepared by solid-phase, room temperature resistivity was 2.7 × 103Ω.cm, Curie temperature is 156 ℃ ,the ratio between the maximum resistance and the minimum resistance was 1.56 × 104 ,temperature coefficient of resistance was 9.19%/℃ Key words: lead-free, PTC, BKT, high-curie temperature III III 目录摘要 I HYPERLINK \l _bookmark0 ABSTRACT II HYPERLINK \l _bookmark1 1 绪论 1 HYPERLINK \l _bookmark2 1.1 无铅 PTC 材料研究意义与研究现状 1 HYPERLI