分步催化制备纳米SiO2减反射膜性质与结构研究.docVIP

分步催化制备纳米SiO2减反射膜性质与结构研究 　　摘要：以正硅酸乙酯和市售硅溶胶为硅源，通过溶胶凝胶法在不同催化条件下制备多孔SiO2减反射膜层，测算了膜层的光学性质及孔隙率，讨论了膜层孔隙构造方式对膜层牢度和耐受性等实用性能的影响.根据讨论结果，采用碱/酸分步催化并引入醇溶性树脂等助剂以改善膜层结构.在光伏玻璃工业辊涂镀膜设备上应用，镀膜光伏玻璃成品的有效透射比达93.7 %，且镀膜面外观、膜层牢度及耐受性等皆复合目前相应产品标准的要求. 　　关键词：反射率；镀膜；耐候性 　　中图分类号：TQ171 文献标识码：A 　　Abstract：Porous SiO2 antireflective coating were obtained through a solgel process using tetraethylorthosilicate and/or commercial nanoSiO2 sol as precursors under different catalytic conditions， the optical properties and porosities of the coated glass samples were measured and calculated. The influences of the porous structure