由二茂铁甲酰基丁酸配体构成的四个新配合物合成和结构毕业论文.doc

Syntheses and structures of four new complexes constructed from ferrocenesuccinic ligand 由二茂铁甲酰基丁酸配体构成的四个新配合物合成和结构 Based on ferrocenesuccinic ligand, four new coordination complexes {[Zn(FcCOC2H4COO)2(pbbbm)](CH3OH)0.5}2 (1), {[Zn(FcCOC2H4COO)2(btx)](H2O)}2 (2), {[Zn(FcCOC2H4COO)2(bbbmd)]}2 (3) and [Cd(h2-FcCOC2H4COO)2(bbbmd)] (4) [Fc = (η5-C5H4)Fe(η5-C5H4), pbbbm = 1,4-bis(benzimid-azole-1-ylmethyl)benzene, btx = 1,4-bis(triazol-1-ylmethyl)benzene), bbbmd = bis-(1-benzoimidazolymethylene)-(2,5-thiadiazoly)-disulfide] have been prepared and characterized. X-ray crystallographic analysis reveals that complexes 1-2 are dimers bridged by btx and pbbbm. Complexes 3-4 are mononuclear structures. Notably, various π-π interactions are discovered in complexes 1-4 and they have significant contributions to molecular self-assembly processes. Furthermore, the thermal analyses results are in reasonable agreement with the crystal structure analysis of complexes 1-4. Keywords: synthesis, crystal structure, π···π interaction, electrochemistry, ferrocenesuccinate. INTRODUCTION During the past decades, great research efforts have been paid to the synthesis of designing intriguing metallosupramolecular complexes with interesting network topologies and/or useful tailor-made properties, such as catalyst, magnetic, and optical properties. Within this field, owing to the fascinating stereochemical and electrochemical properties of aromatic ferrocene,[1] its derivatives have attracted people’s attention[2] and a series of metallosupramolecular complexes containing ferrocene have been reported in recent years.[3,4] Additionally, the coordinating capability of carboxylate groups to metal ions is strong and the coordination modes are also versatile Therefore, it is a good choice to utilize ferrocenyl carboxylates as ligands to synthesize f