一种新型复合结构FRO的合成、结构和热性能英文毕业论文.doc

Article 001 PAGE 2 Undergrad. Chem. Commun. 2010, 1(1), 001-002 Dept. Chem., Zhengzhou Univ. 栏目名 郑州大学标志 [journal], [year], [vol], 00–00 页码 Syntheses, structures, and thermal property of a new complex constructed from ferrocenyl carboxylate ligand ABSTRACT Based on ferrocenesuccinic ligand, a new coordination complex {[Zn(FcCOC2H4COO)2(pbbbm)](CH3OH)0.5}2, [Fc = (η5-C5H4)F e(η5-C5H4), pbbbm = 1,4-bis(benzimid-azole-1-ylmethyl)benzene] have been prepared and characterized. X-ray crystallographic analysis reveals that complex is dimer bridged by pbbbm. Notably, various π-π interactions have significant contributions to molecular self-assembly processes. The thermal analyses results are in reasonable agreement with the crystal structure analysis of the coordination complex. Keywords: synthesis, crystal structure, π···π interaction, ferrocenesuccinate. INTRODUCTION During the past decades, great research efforts have been paid to the synthesis of designing intriguing metallosupramolecular complexes with interesting network topologies and/or useful tailor-made properties, such as catalyst, magnetic, and optical properties.[1-6] Within this field, owing to the better stereochemical and electrochemical properties of aromatic ferrocene,[7] its derivatives have attracted people’s attention[8-10]. Additionally, the coordinating capability of carboxylate groups to metal ions is strong and the coordination modes are also versatile.[11-13] On the other hand, some neutral flexible nitrogen-heterocyclic adjuvant ligands with aromatic systems attract our ongoing interest because of their importance in crystal engineering. Based on foregoing reasons, we utilized ferrocenesuccinic acid and a nitrogen-heterocyclic ligand to react Zn(II) ions and prepared a new complex. Herein, the syntheses, crystal structures, thermal properties of the complex was reported. EXPERIMENTAL General Details Ferrocenesuccinic acid and its co