α-氨基膦酸酯聚合物的合成及其在阻燃和铜离子吸附上的应用-高分子化学与物理专业论文.docxVIP

华 华 中 科 技 大 学 硕 士 学 位 论 文 II II 减小和熵值的增大是凝胶吸附 Cu2+的推动力，且吸附过程以化学吸附为主导，随着 温度升高，吸附量变大；动力学数据表明吸附速率主要受控于扩散过程。 关键词： α-氨基膦酸酯聚合物；Kabachnik-Fields 反应；无卤阻燃；铜离子吸附 III III Abstract The α-aminophosphonates were considered as the analogues of α-amino acids with notable bioactivities and could be used as peptide analogues, catalytic antibodies of hapten, antibiotics and pharmaceuticals. However, there are little researches on synthesis and ap- plication of α-aminophosphonate polymer. In this thesis, two kinds of α-aminophosphonate polymers were prepared and their applications as flame retardant for epoxy resin and adsorption of heavy mental ion were investigated respectively according to their chemical structures. Diethylenetriamine, terephthalic aldehyde and diethyl phosphate were used to synthe- size the polymer, and two methods were adopted. Besides, the three-component, one-pot method—Kabachnik-Fields reaction could synthesize the α-aminophosphonate polymers characterized by FTIR and NMR. The reaction time is a key factor to control the molecu- lar weight of the polymer as well as its distribution. With the polymer added, the bi- sphenol A type epoxy resin could be cured at about 110 ℃ according to DSC results. Samples within more than 20% (weight proportion) polymer could pass UL-94 V test with a classi?cation of V-0. The TG results indicated that within 30% polymer, the char yield at 700 ℃ would reach up to 22.50%. Besides, the DMA results manifested that the Tg of the cured resin would rise as the weight proportion increased. The bending strength and impact strength of the epoxy resins cured with α-aminophosphonate polymer decreased while the bending modulus and compressive modulus increased compared to epoxy resins cured with diethylenetriamine. What’s more, the hydrophobicity of epoxy resins could be maintained according to the contact angle and the moisture adsoption rate was less than 1.2% when the relative humidity was 33, which met the requirement of conventional ap-