Zn-Al-Fe-Ti体系相关系的测定 材料学专业论文.docxVIP

I II Abstract Hot-dip galvanizing is one of the most effective methods for improving the corrosion resistance of steel. Galvalume is one of the hot-dip galvanizing measurement, developed rapidly in recent years, which may substitute the pure znic of the hot-dip galvanizing. Due to the excessive thickness of its coating microstructure and the overabundance bottom dross problems, Galvalumes development is restricted unquestionably. For deeper understanding of the effect mechanism of adding Ti to the Zn-Al alloy, the 600 ℃ isothermal section of Zn-Al-Ti ternary system and rich-Al corner of Zn-Al-Fe-Ti quaternary system with the Al being fixed at 75at.% have been investigated, and using CALPHAD method calculates the phases relation of Zn-Al-Ti ternary system. As result of the existing questionably region of Zn-Ti binary system, this binary system has been analysed and optimized renewedly. In the optimization process of Zn-Ti binary system ， there wasnt any other phase between TiZn3 and TiZn16 ，with the TiZn7 and TiZn8 considered as Ti3Zn22 ，the TiZn15 considered as TiZn16. The transition temperature of the Ti3Zn22 phase was approximately 593℃ in the optimization result, so Ti3Zn22 phase should not exist at 600 ℃ ( ± 5 ℃ temperature error). The 600 ℃ isothermal sections and the phase relations of Zn-Al-Ti ternary system and Zn-Al-Fe-Ti quaternary system were determined by the equilibrated alloys approach, and the specimens were investigated by means of scanning electron microscopy (SEM) equipped with energy dispersive X–ray spectroscopy (EDS) and X–ray diffraction (XRD). Experimental results show that the 600℃ isothermal section of the Zn-Al-Ti system consists of seven ternary phse regions ：TiAl3+T1+α-Al，η-Zn+T1+α-Al，η-Zn+T1+TiZn3， TiZn+T1+TiZn3，T2+T1+TiZn， T2+T1+Ti3Al，TiAl3+T1+TiAl； T1 is in equilibrium with all phase in the system, which has a relatively large composition range of znic and aluminum while tiumium remains nearly between 22.85 ～ 30at.%. W