包钢高炉渣微晶玻璃的热处理制度研究-冶金工程专业论文.docxVIP

内蒙古科技大学硕士学位论文 single-factor studies on the crystallization temperature and the crystallization time at wide ranges, the optimum crystallization temperature range and crystallization time range are identified respectively as 930-990℃ and 30-90min. The optimum isothermal heat- treatment schedule is:crystallizing at 960℃ and thermal insulate for 60min. By this heat- treatment schedule, the glass-ceramics with uniform fine grain can be gained. In this glass- ceramics the glass phase distributes along the grains boundaries and grains ties toughly with each other, and the main crystal phase is diopside alumina, making its flexural strength reached 224.8MPa; (3)By four factors and three levels orthogonal tests L9(34) and results analysis, the optimum step heat-treatment schedule of glass-ceramics is:nucleating at 780℃ for 60min and crystallizing at 960℃ for 60min. By this step heat-treatment schedule the gains in glass-ceramics connect closely and formats clusters, the remaining glass phase content is relatively low and its flexural strength reached 221.7MPa; (4)By comparing the physical properties of glass-ceramics prepared through isothermal heat- treatment schedules and step heat-treatment schedules, and the heat-treatment process cycle time of the two heat-treatment schedules, the isothermal heat-treatment schedules overstep step heat-treatment schedules in the two indexes of mechanical properties and process cycle time. Key words：Blast-furnace slag；Glass-ceramics；Kinetics analysis；Heat-treatment schedules III  目 录 摘 要 I Abstract II 引 言1 1 文献综述2 1.1 我国高炉渣利用现状 2 1.2 微晶玻璃概述 3 1.2.1 微晶玻璃的定义 3 1.2.2 微晶玻璃的性能特点 3 1.2.3 微晶玻璃的分类 4 1.2.4 微晶玻璃的应用 6 1.3 矿渣微晶玻璃的研究现状 7 1.3.1 国外矿渣微晶玻璃的研究现状 7 1.3.2 国内矿渣微晶玻璃的研究现状 8 1.4 矿渣微晶玻璃的制备工艺 9 1.4.1 熔融法 9 1.4.2 烧结法 10 1.4.3 溶胶-凝胶法 11 1.5 微晶玻璃析晶基础理论 12 1.5.1 玻璃的分相 12 1.5.2 玻璃的形核 12 1.5.3 晶体的长大 12 1.6 矿渣微晶玻璃的热处理制度 14 2 选题背景及意义16 2.1 选题背景 16 2.2 研究意义 16 3 研究内容及方法17 3.1 研究内容 17 3.2 实验方案 17  3.2.1 实验设备 17 3.2.2