苯乙烯菜乙烷共聚物超高交联吸附树脂合成及其对茶碱吸附性能研究.docVIP

苯乙烯菜乙烷共聚物超高交联吸附树脂合成及其对茶碱吸附性能研究 　　通讯作者，Email：romann@hunnu.edu.cn（湖南师范大学化学化工学院，中国 长沙410081） 　　摘要采用苯乙烯与1，2双（对乙烯基苯基）乙烷（BVPE）共聚物进行FriedelCrafts后交联，通过对树脂的残留氯含量、比表面积、孔容、孔径及红外光谱等分析表明成功合成了结构均匀的超高交联吸附树脂.并研究该树脂在不同温度下对茶碱的吸附性能.实验表明BVPE树脂对茶碱的静态吸附量可达88.61 mg/g（湿树脂），对茶碱的动态吸附量高于同等条件下合成的DVB树脂，且洗脱容易，对茶碱的脱附率可达99.94%，没有明显的拖尾现象，再生后树脂吸附量大.该树脂的合成解决了现有超高交联吸附树脂结构不均匀、吸附脱附拖尾严重等缺点，是一种性能优良的超高交联树脂. 　　关键词1，2双（对乙烯基苯基）乙烷;超高交联聚苯乙烯;结构均匀性;吸附;茶碱 　　中图分类号TQ034文献标识码A文章编2015 　　Synthesis of Hypercrosslinked Adsorbent Resin Based on 　　the Copolymer of StyreneBis （pvinylphenyl） Ethane and 　　its Adsorption Property for Theophylline 　　ZHONG Shihua， WANG Chunfeng， SONG Qingxia， CONG Fei， GUO Jun， 　　QU Lianghua，XU Mancai* 　　（College of Chemistry and Chemical Engineering， Hunan Normal University， Changsha 410081， China） 　　AbstractIn order to overcome the defects of structural heterogeinity and severe tailing in adsorptiondesorption of commercial hypercrosslinked adsorbent resins，novel hypercrosslinked adsorbent resin with homogeneous structure was synthesized via FriedelCrafts postcrosslinking of styrenebis（pvinylphenyl）ethane copolymers. By measuring the residual content of chlorine， specific surface area， pore volume， pore size and infrared spectrum， the structure of the resin could be analyzed. Furthermore， adsorption behaviors of theophylline onto BVPE resin were tested in aqueous solution. Experiments showed that the BVPE resins static adsorption capacity for theophylline was up to 88.61 mg /g （wet resin）， the dynamic adsorption capacity for theophylline was higher than that of the DVB resin synthesized under the same conditions. Furthurmore， the BVPE resin could be eluted easily and rate of the desorption of theophylline could reach 99.94%.Another advantage was that no significant tailing phenomenon would occur and the adsorption capacity of the regenerated resin was large. 　　Key words1，2bis（pvinylphenyl）ethane; hypercrosslinked polystyrene; structural homogeneity; adsorption;