酸氧化法改性PET薄膜--毕业论文设计.docVIP

PAGE \* MERGEFORMAT II 毕业论文 学生姓名： 学 号： 浦高材070425 所在学院： 南京工业大学浦江学院 专 业： 高分子材料与工程 设计(论文)题目： 酸氧化法改性PET薄膜 指导教师： 2011年4月~2011年6月 摘要 南京工业大学本科毕业论文 PAGE \* MERGEFORMAT I 酸氧化法改性PET薄膜 摘要 聚对苯二甲酸乙二酯(PET)是合成纤维的主要原料之一，它具有耐磨性、耐热性、电绝缘性及耐化学品等优良性能，广泛用于合成涤纶纤维，还可作为工程塑料用于机械、电子、汽车等，在聚酯类产品中占有主导地位，已成为国内外研究的热点。本文主要对PET用硫酸改性方面进行阐述，并对改性后PET做了DSC测定观察其特征温度，红外光谱测量以观察其极性基团，以及改性后PET的拉伸强度以及吸水率的变化。实验结果表明，经酸改性后的PET薄膜，Tm有一定的降低，拉伸强度降低，吸水率增加，PET薄膜的性能有一定的改进。 关键词：PET 硫酸 改性 Modification of PET by acid oxidation technique Abstract Polyethylene terephthalate (PET) is one of the main raw material of synthetic fibers, it has a wear resistance, heat resistance, electrical insulation and excellent chemical resistance and other properties, are widely used in the synthesis of polyester fibers, and also as engineering plastics used in machinery, electronics, automobiles, etc., In the polyester products it has a dominant position, and has become a hot research at home and abroad. This paper focuses on aspects of PET modified with sulfuric acid elaborated, and changes of the Characteristic temperature of modified PET by DSC. Besides,the polar groups are observed by FTIR measurements , as well as the tensile strength of the modified PET are measured by Tensile testing machine.The results showed that the Tm of the acid modified PET film has a certain reduction .The tensile strength has a little decrease,but the water absorption has increaseed.In conclusion,The means can improve the performance of PET film in the way. Key Words: PET；Sulfuric acid；Modification 目录 目 录 摘要······························································I ABSTRACT······················································II 第一章 绪论······················································1 1.1引言·························································1 1.2涤纶改性方法·················································1 1.2.1 共混改性···········