《酸改性粉煤灰吸附除磷性能研究》毕业学术论文.doc

PAGE 攀枝花学院本科毕业论文 酸改性粉煤灰吸附除磷性能研究 学生姓名： 学生学号：200810903031 院（系）：生物与化学工程学院 年级专业：2008级环境工程 指导教师： 讲师 助理指导教师： 二〇一二年六月 攀枝花学院本科毕业设计（论文） 摘 要 Ⅰ 摘 要 我国是个产煤大国，以煤炭为电力生产基本燃料。近年来，粉煤灰的排放量急剧增加，而粉煤灰的综合利用率很低，大量的粉煤灰不仅造成堆积，占用大量土地，而且造成环境的极大破坏，粉煤灰的综合利用迫在眉睫。排入地表水体的磷酸盐是引起水体富营养化的主要因素之一，因此，废水排放时磷的含量需达到国家规定的标准。含磷废水达标排放一般进行深度处理，粉煤灰直接用来处理含磷废水效果不理想。为进一步提高粉煤灰的吸附性能，尝试用酸对粉煤灰改性。 本论文对酸改性粉煤灰吸附除磷性能进行了研究，探究了磷的初始浓度，改性粉煤灰的投加量，反应时间，反应温度，焙烧温度和PH值对吸附效果的影响。实验结果表明：在相同的实验条件下，酸改性粉煤灰对磷的去除率都要好于未改性粉煤灰对磷的去除率。对50mg/L含磷废水，酸改性粉煤灰的投加量为1.5g时去除率为95.62%，吸附时间50分钟时去除率为95.32%，反应温度常温时去除率为94.42%，焙烧温度100℃时去除率为94.33%，PH中性时去除率为92.18%。 关键词 酸改性，粉煤灰，吸附，含磷废水 攀枝花学院本科毕业设计（论文） ABSTRACT Ⅱ ABSTRACT China was a large coal-producing country, the basic fuel of coal for electricity production. In recent years, fly ash emissions sharply increased, and the comprehensive utilization of fly ash was very low, and a lot of fly ash not only caused by the accumulation ,and a lot of land been take up, and caused great damage to the environment, so comprehensive utilization of fly ash became imminent. Discharged into surface water bodies, phosphate was one of the main factors that caused eutrophication, therefore, the content of phosphorus in the wastewater discharge needed to reach the state standards. Phosphorus wastewater discharge standards generally depth treatment of fly ash directly to deal with the phosphorus-containing waste water the result was not ideal. To further enhance the adsorption properties of fly ash, we tried to modify fly ash with acid. In this thesis, discussed the removal of acid-modified fly ash adsorb phosphorus , explored the effect of the phosphorus concentration of the initial dosage of modified fly ash, mixing time, reaction temperature, calcination temperature and PH of the adsorption . experimental results show that: on the same experimental conditions, the acid-mod