MxTiNbO5对甲烷中甲硫醇吸附和光催化性能研究.docVIP

MxTiNbO5对甲烷中甲硫醇吸附和光催化性能研究 　　摘 要: 采用水热法合成层状KTiNbO5,通过离子交换获得Mn0.5TiNbO5和Ni0.5TiN bO5。利用 X-射线衍射(XRD)、紫外-可见漫反射光谱(UV-vis-DRS)、扫描电镜(SEM)、高分辨透射 电镜 (HRTEM)等对催化剂进行表征。采用红外光谱技术考察了催化剂对甲烷气中甲硫醇吸附与 光催化氧化性能。结果表明:在相同层板组成下,层间金属离子不同,对光谱的响应及对有 机硫化物的吸附与光催化氧化能力不同。经Mn??2+和Ni??2+对KTiNbO5 离子交换 后,对光谱吸 收由紫外区移向可见光区;动态条件下,KTiNbO5和Mn0.5TiNbO5虽对甲烷气中的 甲硫醇吸附 很弱,但Mn0.5TiNbO5在自然光与紫外光下对硫醇有催化氧化活性;而Ni0.5 TiNbO5对甲烷气 中的甲硫醇不仅具有良好的吸附活性,且在自然光与紫外光辐射下均显示了良好的光催化氧 化活性。 　　关键词:水热合成; 钛铌酸盐; 甲硫醇; 光催化氧化 　　中图分类号:TQ426文献标识码:A 文章编号:1672-1098(2010)01-0055-05 　　 　　MxTiNbO5 Adsorption and Photocatalytic Capability 　　for Methyl Mercaptan in Methane 　　LU Guo-hui,HE Jie,LAN Yun-xiang 　　(School of Chemical Engineering, Anhui University of Science and Technology, H uainan Anhui 232001, China) 　　Abstract: Layered catalysts M0.5TiNbO5 (M= Mn、Ni) were prepared through Mn??2+an d Ni??2+ ion-exchange of KTiNbO5, which was synthesized by the hydrotherm al synthe sis. The catalysts were characterized by means of powder X-ray diffraction (XR D),UV-visible diffuse reflectance spectroscopy (UV-vis-DRS), Scanning electr onmicroscope (SEM) ,High resolution transmission electron microscope (HRTEM). Theadsorption feature and photocatalytic oxidation activity for mercaptan in methan e over the as-prepared catalysts were evaluated through infrared spectroscopyte chniques. With different cations into the interlayer, the catalysts have differe nt spectral response characteristics, adsorption performance and photocatalyticoxidation activity for mercaptan in methane. After ion-exchange with Mn??2+and Ni??2+, spectral response was shifted from ultraviolet to visible regio n. In dynamicstate, both KTiNbO5 and Mn0.5TiNbO5 have little adsorption activity f or mercapt an, however, Mn0.5TiNbO5 has photocatalytic oxidation activity for merca ptan und er visible or UV light irradiation. Not only the Ni0.5TiNbO5 emerged wel l adsorp tion activity but also photocatalytic oxidation activity for mercaptan in methan e radiated under visible or UV ligh