球磨法磺化聚醚醚酮二氧化硅复合型质子交换膜结构与性能.PDFVIP

Power and Energy Engineering Conference 2010 Performance and Structure of Sulfonated Poly(Ether Ether-Ketone)/Silica Composite Proton Exchange Membrane Synthesized by Ball-Milling 1 1 2 1* Pei-hua CHEN ，Chao YANG ，Xue-hao LIN ， Zhen-tao ZHOU 1College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, P. R. China 2 Shenzhen Meixin Electronics Co. Ltd, Shenzhen 518000, P. R. China E-mail : mcztzhou@ Abstract: In order to study the properties and structure of Sulfonated-poly(ether ether-ketone)/Silica/(SPEEK/SiO2) composite proton exchange membranes （PEM ） prepared by ball milling for direct methanol fuel cell （DMFC ）application,SPEEK/SiO2 Inorganic-Organic composite membranes were prepared with sulfonation degree 75% SPEEK matrix and SiO2 inorganic phase by ball milling.The properties of composite membranes such as conductivity 、methanol permeability 、swelling properties 、 mechanical properties 、SEM and IR were also characterized.The results suggested that SPEEK/SiO2 composite membranes showed a very low methanol permeability,changed between -8 -7 2 1.15×10 ～1.38×10 cm /s ,which was as much as 1-2 orders lower than commercial Nafion117 mem- branes.Composite membranes also exhibited good performance of anti-swelling,its water absorption was only 16.5% and swelling ratio declined to 4.1% at 30 ℃.The tensile strength of composite membranes with 15wt% SiO reached 45.3MPa showed the good mechanical properties of composite membranes.Although