表面活性剂对稀土发光材料形貌性能影响的研究-材料学专业论文.docx

西安建筑科技大学博士学位论文 西安建筑科技大学博士学位论文 西安建筑科技大学博士学位论文 西安建筑科技大学博士学位论文 万方数据 万方数据 万方数据 万方数据 Studies on Functions of Surfactants in the Synthesis of GdVO4:Eu3+ by Hydrothermal Method Specialty: Materials Name: YAN Yinglin Instructor: Prof. XU Yunhua ABSTRACT Rare earth resource was the dominant strategic resource in China. To achieve the development of rare earth resource with high value-added was our urgent strategic target in recent years. The luminescent materials were the most important application area of rare earth resource. The 4f electron configurations in rare earth ions were various. The rare earth luminescent materials possessed excellent luminescence property, multifarious colours and high emission intensity. They were novel functional materials with broad prospect of application, could have been applied in the lighting, display equipments, optical variable inks, agricultural production, biolabeling and clinic trearment areas. During the process of nanomaterials development, to achieve a process route to obtained particles with uniform morphology and grain size, excellent photoluminescent property was still a key problem need to be solved by chemists and materials scientists. The surfactants were the most important factor in the soft chemistry synthesie method that used to prepare functional nanomaterials. The researchment on the influences and action mechanism of the surfactants in solution were not complete system but were of great significance for synthesizing the rare earth functional nanomaterials efficiently and conveniently in future. So it is important to focus on these foundational isssues. This dissertation was focused on the effects of surfactants on the morphology and property of europium doped orthovanadic gadolinium phosphors. The growth mechanism and luminescent evolution were discussed in detail. All the dissertation were mainly divided into six parts: GdVO4:Eu3+ powders were hydrothermally synth esized at 180 °C for 24 h in a wide pH range. The as-sy