过饱和MgSO4溶液结构的X射线衍射研究-中国科学院青海盐湖研究所.PDF

2004 62 Vol . 62, 2004 3 , 268~ 273 ACTA CHIMICA SINICA No. 3, 268~ 273 MgSO X 4 X 房春晖 房 艳 郭亚梅 杨 波 雷亚川 ( 810008) X MgSO 298 K . r = 0. 618K/ in H 4 , r = 0. 618@ 4P/ s . , . Mg- S 0. 328 nm, . Mg2+ Mg-O ( 1) 0. 205 nm, Mg-H O ; Mg- O ( 2) Mg- O ( 3) , 0. 355 nm; Mg- O ( 4) S 2 S S S 0. 456 nm. , . Mg- S 0. 492 nm, . , . , , MgSO , X 4 An X-ray Diffraction Study on the Structure of the Supersaturated MgSO Solutions 4 X FANG, Chun-Hui FANG, Yan GUO, Ya-Mei YANG, Bo LEI, Ya-Chuan ( Institute of Salt Lake, ChineseAcademy of Sciences, Xining 810008) Abstract The hydration tructure of the uper aturated MgSO4 olution ha been inve tigated by mean of X-ray diffraction at 298 K. An empirical golden rule, r = 0. 618K/ in H, ha been u ed to extract ome tructural information from the experimental diffraction curve, and the other, r= 0. 618 @ 4P/ s , to expound ome peak on the tructural function curve. The calculation of the tructural model how there exi t the water- hared ion-pair and the contact ion-pair in the uper a