多孔阳极氧化铝模板的制备表征及特性研究-光伏检测专业论文.docxVIP

上海交通大学硕士学位论文ABS 上海交通大学硕士学位论文 ABSTRACT 第 第 PAGE VII 页 万方数据 FABRICATION, CHARACTERIZATION OF POROUS ANODIC ALUMINA AND ITS SPECIAL PORPERTIES ABSTRACT The PAAs with highly ordered nanopore arrays have attracted more and more attentions, owing their manipulated pores within large range and relatively easy and low-cost processing. The PAAs have diverse applications in the fabrication of nanostructured materials and photonic devices. In this thesis, we focused on an improved two-step anodization technique and the effect of some experimental parameters, as well as the optical constants of the PAA fabricated by the imporved two-step anodization technique and the mechanism of the serreate structure. We gave a brief introduction on the concept of nanotechnology.The main apparatus used for characterizing nanostructured materials were also introduced. Then, the major research developments of PAA films were discussed in details to present a full and accurate knowledge about PAA, including the structure models, formation mechanisms, fabrication techniques, and main applications. We proposed an improved two-step anodization technique through combining the first hard anodization in C2H2O4 with the second mild anodization in H3PO4, which successfully overcome the drawbacks of irregular top surfaces in the conventional two-step hard anodization in C2H2O4 and disordered pore arrays in the two-step mild anodization in H3PO4. The key success of our method is the strong guidance effect of the first hard anodization on the second mild anodization. Highly-ordered (both top and bottom surfaces) porous anodic aluminum (PAA) membranes with interpore spacing from 220-350nm have been realized under anodizing voltages from 100 to 150V. The interpore spacing is only determined by the first anodizing voltage, while the pore diameter can be manipulated in the second step by adding ethanol in the H3PO4 electrolyte, changing the H3PO4 bath temperature, and altering the second anodizing voltag