多孔陶瓷过滤板的制备及性能研究-材料加工工程专业论文.docxVIP

摘 要 本工作采用有机泡沫前躯体浸渍工艺制备了氧化铝质与堇青石质多孔陶瓷过 滤板，利用先进的材料表征手段（DSC、XRD），系统地研究了过滤板的性能，测 试了氧化铝质与堇青石质多孔陶瓷过滤板的孔隙率，探讨了 CeO2 掺杂对堇青石质 多孔陶瓷的烧结相变过程、烧结性能和力学性能的影响。本研究对于开发高孔隙率、 高力学性能的多孔陶瓷有一定的指导意义。 试验结果证明，有机前躯体浸渍法适于制取高气孔率且气孔相互贯通的制品， 其工艺简单，成本低廉。制备过程中前躯体的选择，烧成温度与保温时间都影响着 最终制品的性能。多孔陶瓷的压缩与弯曲强度随着孔隙率升高而下降。 氧化铝质多孔陶瓷的主晶相为刚玉；以 30 ppi 的前驱体制备的过滤板为例，孔 隙率为 88.9 vol %的氧化铝质泡沫陶瓷压缩强度为 3.31 MPa,弯曲强度为 1.69 MPa， 孔隙率为 86.8 vol %的氧化铝质泡沫陶瓷压缩强度达到 3.50 MPa,弯曲强度为 1.91 MPa。抗热震性能良好。 堇青石质多孔陶瓷的主晶相为堇青石，掺杂 CeO2 后，当前躯体为 30ppi 时，制 品的平均压缩与平均弯曲强度分别由原来的 4.01MPa，2.03MPa 提高到 4.20MPa 与 2.10MPa，制品具备良好的抗热震性能。 关键词：多孔陶瓷，堇青石，氧化铝，孔隙率，机械性能，氧化铈 Abstract Polymeric sponge impregnation method was used in this work to prepare Al2O3 and Cordierite porous ceramic filtration boards. Advanced materials study methods (DSC and XRD) were applied in this research to study on the properties of the porous ceramic filtration boards systematically. The porosity of the Al2O3 and Cordierite porous ceramic was also tested. The influence of the CeO2 addition on the transformation in sinter process, the sintering property and mechanical performance of the cordierite ceramic were also determined. This work is of significance and importance to prepare porous ceramic with high porosity and high mechanical performance, to regulate the relationship between porosity and strength, moreover, to exploit new porous ceramic materials. It was showed in the result that polymeric sponge impregnation procedure is an ideal process for preparing porous ceramics, with its simplicity and cheapness. In the preparation, the properties of the final products were affected by the selection of polyurethane, the sintering temperature and the holding time. It can also be found that along with the porosity increasing, the compression and flexural strength decrease accordingly. The main phase of the Al2O3 porous ceramic is corundum. Take the pore size of 30ppi as an example, the compression and flexural strength of the Al2O3 porous ceramic which porosity is 88.9 vol % are 3.31 MPa a