层状钙钛矿氧化物的插层研究无机化学专业论文.docxVIP

中北大学学位论文 中北大学学位论文 研究了 CuCl+对 NaLaTiO4 和 KLaNb2O7 两种层状钙钛矿氧化物的插层。通过 X 射 线粉末衍射对其进行结构表征，分析表明：CuCl+均成功插入到 NaLaTiO4 和 KLaNb2O7 层间，形成了(CuCl)LaTiO4 和(CuCl)LaNb2O7。分别对二者进行结构解析，结果表明 (CuCl)LaTiO4 和(CuCl)LaNb2O7 均为 Aurivillius 相，属四方晶系，I4/mmm 空间群。 (CuCl)LaTiO4 晶胞参数：a=b=3.87 ?，c=21.58 ?，质点数为 2；(CuCl)LaNb2O7 晶胞参 数：a=b=3.88 ?，c = 22.14 ?，质点数为 2。 关键词：层状钙钛矿氧化物，插层，烷基胺，CuCl+ Intercalation Studies of Layered Perovskite Oxides Abstract The layered perovskite oxide is an important solid functional material. Its applications are largely expanded as the layer ,active center of chemical reaction ,due to its unique layered structure. It is widely used in the photocatalysis, ferroelectricity, superconductivity, and semiconductor giant magnetoresistance. This paper focuses on the synthesis and the intercalation reaction with alkyl amines and CuCl+ of three layered perovskite oxides. The synthesis of layered perovskite oxides Three layered perovskite oxides were synthesized by different methods: single-layer Ruddlesden-Popper phase compound NaLaTiO4, three-layer Ruddlesden-Popper phase compound K2La2Ti3O10 and double-layer Dion-Jacobson phase compound KLaNb2O7. The optimum conditions for the synthesis of these three layered perovskite oxide are studied: The calcination temperature should be controlled at 900℃, and the calcination time should be 2h when NaLaTiO4 was synthesized with high temperature solid method;, K should be maintained in 80% excess ,and the precursor must be calcined at 900℃ for 4h when K2La2Ti3O10 was synthesized with the stearic acid method; The precursor should be placed under 1100℃ for 6h when KLaNb2O7 was synthesized with stearic acid method . The study of intercalation of the alkylamine to the layered perovskite oxides The impact of the concentration of H+ and reaction time on intercalation of alkyl amines was studied : the concentration of H+ and reaction time affected the intercalation of alkylamines, mainly through changing the reactivity of the gap between two layers.