油茶果壳中纳米纤维素的分离与成膜性能图5彩印姚进13李知函2.DOCVIP

油茶果壳中纳米纤维素的分离与成膜性能（图5彩印） 姚 进1,3李 知 函2,3史 军 华1,3 曾 广 胜3 朱 和 平1* （1湖南工业大学 包装设计艺术学院，湖南 株洲 412007；2广西清洁化制浆造纸与污染控制重点实验室，广西 南宁 530004；3 湖南工业大学 包装与材料工程学院，湖南 株洲 412007；） 摘要：中英文摘要要一致。答：已做修订，请查阅。以茶籽油生产过程中的废弃物——油茶果壳为研究对象，首先采用亚硫酸盐预蒸煮实现纤维素、半纤维素和木素、茶皂素等组分的分离，然后经硫酸热水解得到油茶果壳纳米纤维素，最后压滤制得高强度透明薄膜。利用SEM、TEM、XRD、TG、UV-Vis、电子万能试验机对纳米纤维素及其薄膜进行了结构表征与热学性能、光学性能、力学性能测试。实验结果表明，从油茶果壳中提取分离得到的纳米纤维素呈棒状，直径为6～10 nm，长度为300～500 nm，属于纤维素I型，结晶度为68%，热分解温度为230 ℃；压滤制备得到的纳米纤维素薄膜，膜厚度为0.03 mm时，在600～800 nm波段处透光率为76%～81%，拉伸强度为75.6 MPa，可用于制备高强度的透明食品薄膜包装材料。 中英文摘要要一致。 答：已做修订，请查阅。 关键词：油茶果壳；纳米纤维素；透明薄膜；生态包装材料 中图分类号：TS71+1 文献标识码：A Structural and Properties of Cellulose Nanocrystals Isolated From the Fruit Shell of Camellia Oleifera Abel Jin Yao1,3 , Zhihan Li2,3 ,Junhua Shi1,3 ,Guangsheng Zeng3 ,Heping Zhu1* 1.School of Packing Design Art，Hunan University of Technology，Zhuzhou Hunan 412007，China 2. Guangxi Key Laboratory of Clean Pulp Papermaking and Pollution Control, Nanning 530004, China 3.School of Packaging and Materials Engineering, Hunan University of Technology, Zhuzhou, 412007, China Abstract: Cellulose nanocrystals (CNC) with high aspect ratio of 50 have been readily prepared from the inexpensive fruit shell of Camellia oleifera Abel (SCOA) for the first time. In this study, SOCA was consecutively subjected to sulfite pulping and acid hydrolysis to remove non-cellulosic components, release CNC and prepare highly transparent film .SEM, TEM, XRD, TG, UV-Vis and Universal strength Testing Machines were used to characterize the internal structure and thermal properties of CNC, the optical properties and mechanical properties of the films .The derived CNC possesses a needle-shaped that in a average diameter and length of 6～10 nm and 300～500 nm, respectively. The XRD result indicated that the CNC belong to I type cellulose and its crystallinity was about 68 %, and the TG testing result showed that the decomposition temperature was 230 ℃.The CNC films that obtained by vacuum filtration showing high trans