二噁英稳定发生源开发及臭氧对萘降解试验研究-工程热物理专业论文.docxVIP

摘要 本文主要针对气相中的多环芳烧类有机污染物，采用臭氧降解技术，研究多 参数对降解效率的影响。同时开发了一种连续、稳定、浓度较高的气相工嗯英发 生源系统，为将来气相中二嗯英降解技术的研究奠定了很好的基础。 采用飞灰索提液往射加热作为气相二嗯英发生源，针头与管攘的残余是影响 索提液中工嗯英挥发的重要问题，加热温度和注射速度是决定索提液中二嗯英挥 发牢的最要因素，试验证明，管内温度为 500 .C，位射速度为O.3mL/min ，载气 流量为 1000mL/min 时，通过改变索提液浓度，二崛英载气浓度可以稳定在 10 -200 ng I-TEQ/Nm3 ，可为以后气相二嗯英降解研究提供较为可靠的发生源。 选取蔡为研究对象，研究臭氧氧化法对气相中多环芳烧有机污染物的降解能 力，并研究了反应混和气体的温度和紫外光照射等因素对降解效率的影响。结果 表明，臭氧对于气相中的蔡有一定的降解能力，徊在浓度与茶相当的情况下效果 并不明显，增加臭氧的浓度可以提高蔡的降解效率，在高臭氧浓度下可以达到 90%的降解效率。增加湿度可以大幅提高臭氧对气相中蔡的降解效率，在 150.C 、 温度 6%、紫外光强度560uW/cm2 (365nm)、停留时间为128 工况下，臭氧均蔡 的浓度比为 1.5: 1 时茶的降解效率可达到 90%。 文中还对下一步工嗯英类有机污染物控制技术研究提出进一步设想。 关键词:二嗯英、琪、气相、降解、臭氧、控基自由基、飞灰索提液、发生源 ABSTRACT Controlling technologies of dioxins in municipal solid waste (MSW)incinerator have been pop topics in environment pollution research all over the world.ηl?s study investigated the application of ozoneωdestruct polycyclic aromatic hydrocarbons (pAHs) in gas phase，and ωnstructed dioxins-containing gas stream generating system wi伽 high concentration for the further investigation of gaseous dioxin control technologies. A stable dioxin generating system has been constructed by heating the stock solution of medical waste fly ashωevapor，时ed dioxins. Remaining dioxins on pinhead and 阳be surface were the major problems. Temperatures (ηand feeding flow rate (v) influence PCDDlFs evaporation. At T=500.C ，when v 口O.2m1/min and N2 gas flowr副e is 1000m1/min，the I-TEQ concentration offlue gas could stay at 10 -200 ng 1-TEQINm3 by changing the concentration of the stock solution injection. ηl?s study investigated the application of ozone in conjunction wi由 water and ultraviolet (UV) to destruct gaseous naphthalene (Nap). The experiments were carried out 创 various constant reaction temperatures (η，inlet concentrations of ozone (C03. in)，intensities of UV and hw旧dity of the gas flow ( wt%).ηle results indicated that ozone had some effects in destructing Nap，but when C03. 而 CNap=1 theωnversion level ofNap (XN叩)wωnot remarkable. XNap i