催化胺化合成2,6-二甲基苯胺的研究化学工程专业论文.docx

increased. 3. Because the Pd-based catalyst price is expensive, so the Ni-based catalyst modified by Cu and Cr for catalytic amination of 2,6-dimethylphenol. And found Ni20Cu10Cr10/γ-Al2O3 exhibited the best activity and selectivity. XRD, XPS, H2-TPR and NH3-TPD were employed for invested the catalyst. It was found that Cu and Cr element are exist in the form of Cu0 and Cr3+ respectively and the addition of Cu and Cr improved the dispersion of the active component Ni and the reducibility of NiO. KEY WORDS： 2,6-dimethylaniline, Pd catalyst, coke deactivation, Ni catalyst 目录 第一章 文献综述 ..................................................................................................... 1 1.1 前言............................................................................................................. 1 1.2 2,6-二甲基苯胺的主要合成方法 ................................................................. 3 1.2.1 间二甲苯硝化还原法 ........................................................................ 3 1.2.2 溴代二烷基特丁基苯胺化法............................................................. 4 1.2.3 苯胺烷基化法.................................................................................... 5 1.2.4 N-甲基邻甲苯胺重排法 7 1.2.5 2,6-二甲基苯酚催化胺化法 ............................................................... 7 1.3 本课题的提出和研究的内容 .................................................................... 10 第二章 实验部分 ................................................................................................... 11 2.1 实验主要原料和试剂的来源及规格......................................................... 11 2.2 催化剂的制备............................................................................................ 12 2.2.1 共沉淀+捏合挤条法 ........................................................................ 12 2.2.2 浸渍法 ............................................................................................. 12 2.3 催化剂的活化............................................................................................ 13 2.4 催化剂的表征..................