反相悬浮法制备淀粉基高吸水性树脂的放大研究及工艺可行性分析-化学工程专业论文.docxVIP

反相悬浮法制备淀粉基高吸水性树脂的放大研究及 工艺可行性分析 摘 要 淀粉基高吸水性树脂是一种具有超强吸水、保水能力的功能高分子材 料，与合成系吸水性树脂相比，具有可生物降解的优势。本文采用反相悬 浮体系将木薯淀粉与丙烯酸、丙烯酰胺两种单体进行接枝共聚制备耐盐性 高吸水性树脂，并将该工艺逐级放大。以放大实验数据为基础，进行中试 放大生产，对影响反应稳定性和树脂吸液水平的因素作适当调整，得出最 佳工艺条件，并对其进行可行性分析。具体研究内容与结果如下： (1) 以 AA(丙烯酸)和 AM(丙烯酰胺)两种物质为单体，对合成耐盐性高 吸水性树脂工艺条件讨论得出：AA 与 AM 质量比为 4，AA 的中和度为 80％， 引发剂 KPS(过硫酸钾)为单体总量的 5.4wt.％，交联剂 MBA(N,N’-亚甲基双 丙烯酰胺)为单体总量的 0.028wt.％，环己烷与水的体积比为 2:1，分散剂 Span80 与 Tween80 的质量比为 3:1，分散剂总量占单体总量的 8.8wt.％，聚 合反应搅拌转速为 220rpm 时，树脂吸去离子水率 1280g·g-1，吸 0.9 wt.％ NaCl 溶液率 88 g·g-1。 (2) 依据逐级放大结果，进行中试放大生产，并调整交联剂用量为单体 总量 0.032wt.％，Tween80、Span80、PEG-4000(聚乙二醇-4000)、PDMS(聚 二甲基硅氧烷)四元复合分散剂的投料比例调整为 1:4:12:10，搅拌转速调整 在 50～80 rpm 时，反应体系稳定，树脂性能经检测达标，吸去离子水率 1064g·g-1， 吸 0.9wt.％NaCl 溶液率 86 g·g-1。 (3) 以中试数据及市场现状为参考，对反相悬浮法制备淀粉基高吸水性树 脂工艺进行可行性分析，得出工艺路线及各项指标均符合可行性要求。 关键词：高吸水性树脂 耐盐性能 逐级放大 中试生产 可行性分析 AMPLIFICATION OF PREPARATION OF STARCH-BASED SUPERABSORBENT BY INVERSE SUSPENSION GRAFT COPOLYMERIZATION AND FEASIBILITY ANALYSIS ABSTRACT Starch-based superabsorbent is a kind of super absorbent and water retention ability functional polymer materials. It has a great advantage of biodegradation compared with the synthesized superabsorbent resin. In this paper, cassava starch was used as row materials to prepare salt-tolerance starch-based superabsorbent by inverse suspension graft copolymerization with acrylic acid and acrylamide monomers. Pilot production was carried out based on the experimental data of progressively amplification. Factors affecting the reaction stability and liquids absorption level of resin were adjusted to get the optimal technological conditions. And the feasibility analysis on the industrialization process was also investigated. The research contents and results are as follows: With AA and AM as monomers, the synthesis conditions of salt-tolerance starch-based superabsorbent resin were: the mass ratio of AA and AM was 4, neutralization degree of AA was 80 %, initiator KPS and crosslinking agent MBA were 5.4wt.% and 0.028wt.% of the total