碳材料掺杂对镁基氢化物释氢性能的影响及其微观-中国有色金属学报.PDF

25 9 2015 9 Volume 25 Number 9 The Chinese Journal of Nonferrous Metals Sep. 2015 1004-0609(2015)-09-2464-07 1, 2 1 1 3 , , , (1. 410114 2. 410114 3. 410082) MgH MgH -10%( 2 2 )MgH2-10%3 XRDSEMDSC−TG MgH2 MgH2 MgH2 33 MgH2 MgH2 Mg—H H MgH2 MgH2 TG139.7 A Influence and micro-mechanism of carbon materials doping on dehydrogenation properties of magnesium based hydride 1, 2 1 1 3 ZHANG Jian , ZHU Pu , MAO Cong , ZHOU Dian-wu (1. Key Laboratory of Lightweight and Reliability Technology for Engineering Vehicle, Education Department of Hunan Province, Changsha University of Science and Technology, Changsha 410114, China; 2. Key Laboratory of Efficient and Clean Energy Utilization, Education Department of Hunan Province, Changsha University of Science and Technology, Changsha 410114, China; 3. State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, Hunan University, Changsha 410082, China) Abstract: The pure MgH , MgH -10% graphite (mass fraction) and MgH -10% graphene hydrogen storage systems were 2 2 2 prepared by mechanical ball-milling technology with two kinds of carbon materials such as graphite and graphene as the dopants. Using the XRD, SEM, DSC−TG experimental test