溴氰菊酯残留测定的方法及其在金银花中残留动态的研究.docVIP

溴氰菊酯残留测定的方法及其在金银花中残留动态的研究 　　[摘要]研究溴氰菊酯在金银花中的残留动态规律，为金银花安全监控及生产中的安全合理使用提供科学依据。采用田间试验方法，设对照、喷施推荐剂量、高倍剂量共3个处理，重复3次。于喷施农药后2 h，1，2，3，4，5，7，9，11，13，15 d，采集样品。建立气相色谱测定方法对田间样品进行测定。结果表明，建立的金银花中溴氰菊酯测定法，在3个不同添加水平溴氰菊酯回收率均在764%～869%，RSD小于11%，在5～500 μg?L-1线性关系良好，符合农残测定要求；田间试验得到残留动态方程为高倍剂量C=5992 2e-0338t，推荐剂量C=1536 9e-031t，残留动态符合一级动力学降解规律，农药半衰期为209～224 d。建议在蚜虫发生期按推荐剂量喷施溴氰菊酯乳油，距离采花至少间隔7 d，以保证金银花药材安全。 　　[关键词]金银花；溴氰菊酯；残留动态；农药安全使用；农药半衰期 　　[Abstract]This paper reports the residual dynamics of deltamethrin and detection method in Loincerae Japonicae Flos to provide scientific basis for safe and appropriate use of deltamethrin A field experiment was conducted in Fengqiu， Henan Province China The field plots were sprayed with deltamethrin at the recommended dose and a high dose， respectively， and a control was set up， totally being 3 treatments with 3 replications The flowers were picked at 2 hours， 1， 2， 3， 4， 5， 7， 9， 11， 13 and 15 days after pesticide application and then dried The residue of deltamethrin was determined by gas chromatography method with electron capture detector for the above samples Results showed that recoveries of deltamethrin ranged from 764% to 869%，and the relative standard deviation was below 11%，Linearity was observed over a range of 5500 μg?L-1 with correlation coefficient was 0 999 2 The established method meets the requirements of pesticide residue analytical methods The degradation of deltamethrin followed the first order dynamics The residue dynamic equation of the high dose and recommended dose deltamethrin were C=5992 2e-0338t and C=1536 9e-031t respectively， and the halflife of deltamethrin in Loincerae Japonicae Flos was 209224 days， which indicates that deltamethrin is an easily degradable pesticide It is concluded that deltamethrin should be used in aphids occurring period and the safety interval was more than 7 days to ensure the safety of Loincerae Japonicae Flos consuming 　　[Key words]detalmethrin； Loincerae Japonicae Flos； residual dynamics；