钢铁制程废弃物应用於碳捕获之绩效评价及其再-中国鑛冶工程学会.PDF

鋼鐵製程廢棄物應用於碳捕獲之績效評估 及其再利用之潛勢分析 Assessment of Using Alkaline Wastes from Steelmaking Process for Carbon Capture and Resource Reutilization 1 2 3 4 S.Y. Pan, P.C. Chiang, C.D. Chen, H.Y. Lin C O2 c ap t u r e b y c ar b on at i on o f b a si c ox y g en furnace (BOF) slag in a rotating packed bed (PRB) is sup erior to that in the traditional reactor s du e to the relatively short reaction time at ambient temperature and pressure. However, grinding BOF slag and additional energy consumption are required to promote the overall carbonation efficiency for the RPB process. The cold- rolling mill wastewater (CRMW) from the steelmaking X process was utilized as the liquid phase to increase the carbonation efficiency and reduce the use of fresh resource. The net CO2 capture capacity of the process was evaluated by life cycle assessment (LCA). Results indicated that the CRMW could effectively enhance the dissolution of metal 1-3 μm ions from BOF slag into solution, thus the CO2 capture (CaCO3) capacity of BOF slag. The reaction product formed was free-CaO mainly calcite (CaCO3) with particle size ranged between 1 and 3 μm . The content of free-CaO in BOF slag was found to be eliminated after carbonation. The RPB process could capture the CO2 from flue gas, neutralize the alkaline CRMW, and stabilize the BOF slag for further utilization. 關鍵詞： Key words: b asic oxygen furnace slag, carb onation