碳纳米管的化学改性、结构表征和性能-研究.pdf

华东师范大学硕士论文 Abstract Inthis carbonnanotubeswere and thesis，towith，solube begin prepared most conditionto thecarbon characterized．Then，the optimized modify nanotubeswhile theinherent ofMWNTsasmuchas keeping properties was resultswereobtained： possibleinvestigated．Thefollowing 1．Aseriesof multi-walledcarbonnanotubes octadecy’lamine(ODA)grafted andcharacterized andXRD．Itis NMR，FTIR，DSC (MWNT)wereprepared by revealedthattheODAchains onMWNTare grafted partiallycrystallized， the structureisnotas asthe ODA．Itisbelieved thoughpacking perfect pure thalODA toreactatsomeactivesites．suchasthetube—endsandthe prefer defectsonthesidewallofMWNT．A NMR was technique quantitative todeterminethe ofODAinmodifiedMWNT．The developed weightpercent betweenthecontentofODAandthe ofsolubleMWNTs relationship solubility iSdiscussed． 2Multi—walledcarbon oxidizedandshortenedwith nanotubes(MWNTs)were amixtureofconcentratedSUIfuricandnitricacidsunder sonication，to introduce and onto carboxylhydroxylgroups and1 NMR