稀土-2_2′-联苯二甲酸配合物的合成、结构及发光性能研究论文-毕业论文（设计）.docVIP

l 稀土-2，2′-联苯二甲酸配合物的合成、结构及发光性能研究 摘要: 本文采用水热法合成了三个稀土配位聚合物：[Ln2(H2O)2(dpa)3]（Ln=Sm（1），Eu（2），Tb（3））（dpa=2，2′-联苯二甲酸），并采用单晶X-射线衍射、红外光谱、差热-热重、粉末衍射、荧光光谱等手段对三个配合物的结构及性质进行了研究。单晶X衍射分析表明2，2′-联苯二甲酸与Ln3+离子相连形成了一条无限延伸的一维Ln-O-Ln链。荧光分析表明，dpa配体对铕离子和铽离子的发光均有较好的敏化作用，配合物均表现出比较强的荧光性质。配合物2在激发波长315nm (λmax=544nm) 下发出强烈的绿光，配合物3在激发波长336nm (λmax=616nm) 下发出强烈的蓝光。 关键词: 水热法合成；2，2′-联苯二甲酸；稀土配合物；荧光光谱 Abstract:Three rare-earth complexes formulated as [Ln2(H2O)2(dpa)3]（Ln=Sm（1），Tb（2），Eu（3））（dpa=2，2′-diphenic acid）have been hydrothermally synthesized．The structures and properties of all the complexes were characterized by single-crystal X-ray、IR、TGA、powder XRD and photoluminescence studies.Single crystal X-ray studies shows that the compound has infinite Ln-O-Ln one-dimensional chains resulting from a bonding between Ln3+ cations and diphenate anions. Fluorescent analyses show that Tb3+ and Eu3+ can sensitize strong metal-centered luminescence by ligand-to-metal energy transfer. Complex 2 exhibits intense green luminescence (λmax=544nm) upon excitation at 315 nm and complex 3 exhibits intense blue luminescence (λmax=616nm) upon excitation at 336 nm． Keywords: Hydrothermal synthesis；2，2′-diphenic acid；rare-earth complexes；Fluorescence 目录 1 引言..........................................................................................................3 2 实验部分..................................................................................................4 2.1 试剂..................................................................................................4 2.2 仪器设备..........................................................................................5 2.3 测试方法..........................................................................................5 2.4 配合物的合成..................................................................................6 2.5 配合物的晶体结构分析..................................................................6 3 结果与讨论..........................................................