《二氧化钛论文：纳米二氧化钛的水热制备及光激发特性研究》-毕业论文.docVIP

l 二氧化钛论文：纳米二氧化钛的水热制备及光激发特性研究 【中文摘要】二氧化钛(TiO2)做为重要的宽禁带n型半导体材料,有着稳定性高、无毒、紫外吸收等特性,在环境、材料、能源、生物与卫生等领域,应用前景都很广阔。近年来,纳米技术得到了飞速的发展,研究纳米Ti02粉末的越来越多,但粉末没有承载体,不利于回收在利用,限制了其应用。所以本文将纳米TiO2与钛合金有机结合,原位制备纳米Ti02薄膜材料。首先从理论上对水热法制备纳米TiO2薄膜的生长机理进行了探讨,分析了其生长特性的影响因素；然后,以Ti (SO4)2为原料,无水碳酸钠(Na2CO3)为添加剂,采用水热合成法在钛合金基底上成功制备了锐钛矿相的纳米二氧化钛(TiO2)薄膜。利用X射线衍射(XRD)、扫描电子显微镜(SEM)等手段系统的研究了前驱体浓度和反应参数(反应时间、反应温度)对纳米TiO2薄膜生长特性、结晶特性和相组成的影响规律,分析了其动力学机制；最后,利用紫外可见光分光光度计(UV-Vis)、光致激发光谱(PL)等手段研究了所制备TiO2薄膜的光吸收和光激发特性,并通过微观机制对其影响规律进行了理论解释。 【英文摘要】As an important wide band gap n-type semiconductor material, Titanium dioxide (TiO2)has the characteristics of high stability, non-toxic, UV absorption, who’s prospects are very broad and can be used in the fields of environment, materials, energy, biological and health. Recently, with nanotechnology developed rapid the researches of nano-TiO2 powder are increasing, but it make against recycling because it has not supporting body, so limiting its application.This paper has combined nano-TiO2 with titanium and in situ preparation nano-TiO2 thin films. First, hydrothermal prepared growth mechanism of nano-TiO2 thin films has been discussed, and the impact factors of the growth characteristics has been analyzed; Then, use Ti(SO4)2 as the raw material and anhydrous sodium carbonate(Na2GO3) as the additive, prepared anatase titanium dioxide (T1O2) thin films by using the method of hydrothermal synthesis on the substrate of titanium successfully. The law of concentrations and reaction parameters(reaction time, reaction temperature) effect on the growth characteristics of nano-TiO2 thin films、the crystallization and phase composition has been studied systematically by used the method of X-ray diffraction(XRD) and scanning electron microscopy(5EM), the dynamics mechanism has been analyzed; Finally, the characteristics of optical absorption and excitation of prepared TiO2 thin films has been studied use of UV-visible spectrophotometer (UV-Vis) and photoluminescence spectroscopy (PL),