优秀（设计）碳基固体酸催化合成环己酮甘油缩酮工艺研究.docVIP

本研宂以太西煤基活性炭和苯胺单体为原料，通过原位-溶液聚合法制备出聚苯胺薄膜 包覆活性炭的复合型高酸值核壳结构碳基固体酸AC@PANI-SO3H(APS),通过SEM、TEM、 IR及XRD催化剂表面形貌结构和化学特性分析表征结果表明，自制聚苯胺包覆太西煤基活 性炭固体酸催化剂表现出较高的催化活性和稳定性。在催化剂用量0.1 g,环己酮与甘油摩 尔比1丄2,带水剂用量10 mL,反应时间为1.5 h的最佳反应条件下，环己酮转化率达97%? 99%,主产物选择性为98.5%。催化剂重复使用4次以后催化活性下降。此外，通过IR和酸 密度测试分析了催化剂失活的主要原因。 关键词：催化剂APS碳基固体酸环己酮甘油缩酮催化剂失活 Abstract This study the etheric west coal based activated carbon and aniline monomer as raw material, through the in situ - solution polymerization of the polyaniline film coated activated carbon prepared by the composite core-shell structure with high acid value of carbon-based solid acid AC@PANI.SO3H (APS), through SEM, TEM, IR and XRD characterization of catalyst surface morphology structure and chemical properties analysis results show that the self-made polyaniline coated too west coal based activated carbon solid acid catalyst showed high catalytic activity and stability. In catalyst 0.1 g，cyclohexanone with glycerin mole ratio of 1:1. 2, the dosage of 10 mL water, the reaction time was 1.5 h under the optimum reaction conditions, cyclohexanone conversion rate was 97%-99%, the main product selectivity of 98.5%. Catalyst reusable catalytic activity down after four times. In addition, by IR and acid density test and analysis of the main causes of catalyst deactivation. Key words: Catalyst APS carbon based solid acid Cyclohexanone glyceryl ketal Deactivation of catalyst TOC \o 1-5 \h \z 会者i仑 1 1. 1 HUa 1 HYPERLINK \l bookmark3 \o Current Document \h 1.2国内外研宂 1 HYPERLINK \l bookmark4 \o Current Document \h 1.3目的和意义 2 HYPERLINK \l bookmark5 \o Current Document \h 催化剂的制备 4 HYPERLINK \l bookmark6 \o Current Document \h 2.1制备工艺优越性比较 4 HYPERLINK \l bookmark7 \o Current Document \h 2.2酸密度测定 4 HYPERLINK \l bookmark8 \o Current Document \h 2.3催化剂制备 4 HYPERLINK \l bookmark9 \o Current Document \h 2.4催化剂表征 5 2.4.1催化剂表面化学特性研究 5 2.4.2催化剂表面形貌和结构研宄 6 1 HYPERLINK \l bookmark11 \o Current Document \h 3.1原料与仪器 1 HYPERLINK \l bookmark12 \o Current Document \h 3