带钢表面析碳的热力学分析及Zn基合金热力学数据库的建立-材料学专业论文.docx

湘潭大学硕士学位论文AB 湘潭大学硕士学位论文 ABSTRACT II II ABSTRACT Hot-Dip galvanizing is widely used for improving atmospheric corrosion resistant of steel parts. Imperfect adhesion of coating and Dezincification of strips always occur in modified Sendzimir-type hot-process continuous galvanizing line. In most cases this phenomenon is the result of the changes of technical parameter of nonoxidizing furnace. The fluctuation of nonoxidizing furnace (NOF) ambient atmosphere and the unreasonable tapping temperature will all affect the surface condition of the strip, causing carbon precipitation on the surface of strip or excessive oxidation. These carbon grain and oxidized film could result in imperfect adhesion. By analyzing the fluctuation of Coke-Oven Gas (COG) composition in annealing furnace of continuous galvanizing production line (CGL) which belonged to Liansteel, The mechanism of carbon precipitation on the surface of strip was researched, a mathematical calculation for carbon precipitation on the surface of strip was modeled using Factsage Thermochemical Software and a complete curve of relation among air ratio, strip temperature and carbon precipitation area was derived. This model also quantificationally analyzed the influence of the fluctuation of coke oven gas (COG) composition on the temperature when carbon first precipitates. This can assist in adjust air ratio to control the strip surface condition and determine the appropriate strip tapping temperature. Those conclusions afford benefit for appropriate technology selection. Alloy elements play a key role for controlling the coating quality. The study of zinc alloy systems and the growth law of coating from thermodynamic calculation can help us to predict and control the product process. There’s very important meaning for controlling the quality of galvanizing products, optimizing the galvanizing process parameters and facilitating the development of galvanizing industry. But during the hot-dip galvanizing process, the re