分子印迹导电聚苯胺电极柱分离氨基酸光学异构体-化学工艺专业论文.docx

PAGE PAGE VI For broadening the scope of application of polyaniline in the aspect of pH, a copolymer (aniline-co-m-aminophenol) has been synthesized via the method of chemical oxidation combined with molecularly imprinted technology. The cyclic voltammograms of the copolymer expatiated that its dependence on pH values was decreased comparaed with PANI. Then the EQCM was used to optimize the doping/de-doping condition, and molecularly imprinted copolymer electrode column was used to separate glutamic acid enantiomers in the optimal conditions. The chiral selectivity factor of glutamic acid enantiomers in this electrode column can reach 2.38. This kind of separation amino acid optical isomers using molecularly imprinted conductive polymer electrode column has many anvantages, such as simple operation, without pollution, and lower cost. KEY WORDS: amino acid enantiomers; molecular imprinting technique; conductive polymer; chirial separation; electrode column 目录 中文摘要 III ABSTRACT IV HYPERLINK \l _bookmark0 目录 VI HYPERLINK \l _bookmark1 1 绪 论 1 HYPERLINK \l _bookmark2 1.1 手性物质的分离 2 HYPERLINK \l _bookmark3 1.1.1 手性物质的定义及其特点 2 HYPERLINK \l _bookmark4 1.1.2 手性物质的分离方法 2 HYPERLINK \l _bookmark5 非色谱法 2 HYPERLINK \l _bookmark6 色谱法 4 HYPERLINK \l _bookmark7 1.2 分子印迹技术 6 HYPERLINK \l _bookmark8 1.3 导电聚合物的发展 7 HYPERLINK \l _bookmark9 1.3.1 导电聚苯胺的结构、导电机理及掺杂机制 8 HYPERLINK \l _bookmark10 1.3.2 导电聚苯胺的制备方法 9 HYPERLINK \l _bookmark11 化学合成法 9 HYPERLINK \l _bookmark12 电化学合成法 10 HYPERLINK \l _bookmark13 1.3.3 分子印迹导电聚合物的应用 10 HYPERLINK \l _bookmark14 1.4 本文研究内容 11 HYPERLINK \l _bookmark15 1.4.1 研究目的 11 HYPERLINK \l _bookmark16 1.4.2 研究内容 11 HYPERLINK \l _bookmark17 2 分子印迹导电聚苯胺(MICPs)的制备及采用 pH 调控法分离天冬氨酸(Asp)光学异 HYPERLINK \l _bookmark17 构体 12 HYPERLINK \l _bookmark18 2.1 引言 12 HYPERLINK \l _bookmark19 2.2 实验部分 12 HYPERLINK \l _bookmark20 2.2.1 仪器与试剂 12 HYPERLINK \l _bookmark21 实验仪器 12 HYPERLINK \l _bookmark22 实验试剂 13 HYPERLINK \l _boo