超音速火焰喷涂热障涂层抗氧化性能及热震性能的研究-材料加工工程专业论文.docxVIP

超音速火焰喷涂热障涂层抗氧化性能及热震性能的研究 超音速火焰喷涂热障涂层抗氧化性能及热震性能的研究 RESEARCH ON HVOF SPRAYED THERMAL BARROER COATINGS FOR OXIDATION RESISTANCE AND THERMAL SHOCK PROPERTIES ABSTRACT Thermal barrier coatings (TBCs) have excellent properties of resistance high temperature oxidation, were widely used in aero-engine turbine blades, can reduce surface temperature of the blades and prolong the service life of coatings. Further improving thermal barrier coating high temperature oxidation resistance become important research subject. Thermal barrier coatings were deposited onto GH4099 high-temperature alloy using high velocity oxygen furel (HOVF) technique with MCrAlY bond coat and 8YSZ top layer, its resistance of high temperature oxidation and Thermal cycling was studied. scanning electron microscope, ruby fluorescence spectroscopy(RFS),XRD diffraction, EDS and other detection methods were used to analysis the microstructure, high temperature oxidation behavior and failure behavior of coatings. The results showed that: technology of HVOF can significantly improve rough interface APS bond layer, access to more flat interface，small particles can increase the interface,then greatly increased the spread channel of Al element in coat , help to form Al2O3 lay cover on the surface of bond layer, And the time of TGO coming into steady-state oxidation stage was shortened and the period of steady-state oxidation become more longer ,avoid forming of large loose oxide particles of spinel oxide, reducing the formation of oxide defects, great increase the service life of thermal barrier coatings. HVOF coating will quickly form TGO on the interface of ceramic layer and bond layer in initial oxidized stage, after 96 hours oxidation, TGO appears delamination , the inner surface of TGO to isometric crystal growth, composed by dense Al2O3 ; while the external surface of TGO was columnar crystal growth, more big gaps were appeared in the coating . HVOF coatings stress growth was relatively stable and have no